Two New Hybrid lodoplumbates with Chain-like Cations

被引：19

作者：

Zhang, Bo ^{[1
,2
]}

Li, Jun ^{[1
,2
]}

Li, Lian-Zhi ^{[1
]}

Ren, Xiao-Chen ^{[1
]}

Pang, Ming ^{[1
]}

Shao, Ya-Nan ^{[1
]}

机构：

[1] Liaocheng Univ, Sch Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2021年 / 21卷 / 09期

关键词：

OPTICAL-PROPERTIES; CRYSTAL-STRUCTURES; IODOPLUMBATE; BROMIDES; COMPLEXES;

D O I：

10.1021/acs.cgd.1c00634

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By utilizing in situ-formed MCP ligands (HMCP+ = 1-methyl-4-(carboxyl)pyridinium) as decoration agents, two new iodoplumbate hybrids, namely, [Pb(MCP)(2)I]PbI3 (1) and Cs-2[Pb(MCP)(4)]Pb3I10 (2), have been solvothermally prepared and structurally characterized. Compound 1 features the typical one-dimensional (1D) [PbI3](n)(n-) anions, while compound 2 exhibits two-dimensional (2D) [Pb3I10](n)(4n-) slabs perforated with large parallelogram-shaped windows. The intriguing structural characteristic of compounds 1 and 2 is that they contain unique chain-like cations of [Pb(MCP)(2)I](+) and [Pb(MCP)(4)](n)(2+), respectively. Interestingly, upon alternate visible-light and full spectrum light irradiation, compounds 1 and 2 show stable and rapid photoelectric switching properties, whose photocurrent densities are comparable or larger than those of many metal halide hybrids. Additionally, their optical properties, Hirshfeld surface analyses, X-ray photo-electron spectra, as well as the theoretical band structures and density of states have also been studied.

引用

页码：5317 / 5324

页数：8

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