Selective benzylic C-C coupling catalyzed by a bioinspired dicopper complex

被引：27

作者：

Prokofieva, Angelina ^{[1
]}

Prikhod'ko, Alexander I. ^{[1
]}

Dechert, Sebastian ^{[1
]}

Meyer, Franc ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 08期

关键词：

D O I：

10.1039/b718162k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly preorganized bioinspired dicopper complex with imidazole ligation catalyzes the selective benzylic para-C-H activation of 2,4,6-trimethylphenol under aerobic conditions, yielding either the stilbenequinone or 4-methoxymethyl-2,6-dimethylphenol depending on the solvent used.

引用

页码：1005 / 1007

页数：3

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