Selective benzylic C-C coupling catalyzed by a bioinspired dicopper complex

被引：27
|
作者：
Prokofieva, Angelina [1 ]
Prikhod'ko, Alexander I. [1 ]
Dechert, Sebastian [1 ]
Meyer, Franc [1 ]
机构：
[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany
来源：
CHEMICAL COMMUNICATIONS | 2008年 / 08期
关键词：
D O I：
10.1039/b718162k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A highly preorganized bioinspired dicopper complex with imidazole ligation catalyzes the selective benzylic para-C-H activation of 2,4,6-trimethylphenol under aerobic conditions, yielding either the stilbenequinone or 4-methoxymethyl-2,6-dimethylphenol depending on the solvent used.
引用
收藏
页码：1005 / 1007
页数：3
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