Synthesis and crystal structure of complex [Nd(2-FC6H4COO)3•(2-FC6H4COOH)•H2O]2

被引：3
|
作者：
Li, Xia [1 ]
Zou, Ying-Quan
Song, Hai-Bin
机构：
[1] Capital Normal Univ, Dept Chem, Beijing 100037, Peoples R China
[2] Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China
[3] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2007年 / 37卷 / 08期
关键词：
neodymium complex; 2-fluorobenzoic acid; crystal structure;
D O I：
10.1007/s10870-007-9210-0
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The neodymium complex with 2-fluorobenzoic acid was synthesized and characterized by X-ray diffraction. The complex crystallizes in the triclinic system with space group P1, lattice parameters: a = 9.2747(10) angstrom, b = 11.7594(13) angstrom, c = 13.5158(14) angstrom, alpha= 110.220(2)degrees, beta= 93.930(2)degrees, gamma= 90.894(2)degrees, V = 1378.8(3) angstrom(3), Z = 1, Dcalc = 1.733 Mg/m(3). The complex is a binuclear molecule in which four 2-fluorobenzoato groups act as bidentate and tridentate bridges between the two Nd3+ ions. Each Nd3+ ion is additionally chelated by one 2-fluorobenzoato group and coordinated by one 2-fluorobenzoic acid and one water molecule.
引用
收藏
页码：555 / 559
页数：5
相关论文
共 50 条
  • [21] Crystal structure and characterization of the dinuclear Cd(II) complex [Cd(H2O)2(o-HOC6H4COO)2]2
    Jian, FF
    Xiao, HL
    Sun, PP
    Zhao, PS
    MOLECULES, 2004, 9 (10): : 876 - 882
  • [22] Synthesis, Crystal Structure and Luminescene Spectrum of a Binuclear Complex [Eu2(HOC6H4CH2COO)6(C10H8N2)2(H2O)2]•H2O
    Zhang, Hong-Xun
    Guan, Quan-Yin
    Zhao, Guo-Liang
    ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (07) : 3613 - 3616
  • [23] Synthesis, Structure and Characterization of a New Complex: [Mn(C6H12N4)2(H2O)4][Mn(H2O)6][SO4]2·6H2O
    李登鹏
    许智煌
    叶李旺
    曹腾飞
    庄欣欣
    Chinese Journal of Structural Chemistry, 2021, 40 (09) : 1169 - 1176
  • [24] Synthesis, Crystal Structure and Electrochemical Properties of Complex [Ni（2,2’-bipy）2（ClC6H4COO）(H2O)]（ClO4）
    李薇
    李昶红
    郭栋才
    杨颖群
    Chinese Journal of Structural Chemistry, 2006, (04) : 387 - 391
  • [25] Synthesis, crystal structure and electrochemical properties of complex [Ni(2,2′-bipy)2(ClC6H4COO)(H2O)](ClO4)
    Li, W
    Li, CH
    Guo, DC
    Yang, YQ
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2006, 25 (04) : 387 - 391
  • [26] Synthesis and Crystal Structure of Co（C6NO2H4）3. H2O
    ZI Feng-Lan
    ZHOU Yin-Zhuang
    TU Shu-Jie
    LIU Shun-Cheng(Department of Chemistry
    Chinese Journal of Structural Chemistry, 1997, (05) : 376 - 379
  • [27] The Crystal Structure of Indium Perchlorates [In(H2O)6](ClO4)3 and [In(H2O)6](ClO4)3 • 3H2O
    Ilyukhin, A. B.
    Malyarik, M. A.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 1999, 44 (04) : 476 - 479
  • [28] Synthesis and crystal structure of [Yb(NTO)3(H2O)4]&middot6H2O
    Northwest Univ, Xi'an, China
    J Rare Earth, 1 (62-65):
  • [29] ON CRYSTAL STRUCTURE OF NA2H2GEO4(H2O)6
    BAUREN, EB
    INGRI, N
    ACTA CHEMICA SCANDINAVICA, 1967, 21 (09): : 2511 - &
  • [30] Synthesis and crystal structure of europium(II) tartrate tetrahydrate, [Eu(C4H4O6) (H2O)2](H2O)2
    Starynowicz, P
    Meyer, G
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2000, 626 (12): : 2441 - 2442
12345