Macroscopic Chiral Recognition by Calix[4]arene-Based Host-Guest Interactions

被引：24

作者：

Quan, Jiaxin ^{[1
]}

Nie, Guanrong ^{[1
]}

Xue, Hong ^{[1
]}

Luo, Li ^{[1
]}

Zhang, Ruiping ^{[2
]}

Li, Haibing ^{[1
]}

机构：

[1] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol CCNU, Wuhan 430079, Hubei, Peoples R China

[2] Shanxi Med Univ, Imaging Dept, Affiliated Tumor Hosp, Taiyuan 030001, Shanxi, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2018年 / 24卷 / 58期

基金：

中国国家自然科学基金;

关键词：

chiral matching; host-guest systems; macroscopic recognition; supramolecular chemistry; surface chemistry; SELF-ASSEMBLED MONOLAYERS; DRUG-DELIVERY; SURFACE; MODEL; AGGREGATION; INTERFACES; TRANSPORT; CHEMISTRY; MEMBRANES; SELECTION;

D O I：

10.1002/chem.201803564

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chiral recognition as an intrinsic process of life, plays a crucial role in chemical systems, and further forms various architectures in the resulted functional materials. So far, relevant studies were focused on the recognition of chiral molecules. However, weak chiral interactions transformed into macroscopic recognition, for example, for chiral drug droplets, is much more crucial due to its applicability in controlling the drugs selective delivery and for their enantiomer separation. In this report, chiral calix[4]arene was introduced onto a surface for the selective recognition of (S)-naproxen droplet through host-guest interactions.

引用

页码：15502 / 15506

页数：5

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