Synthesis and characterization of a three-dimensional porous compound:: [Cu(H2O)6][{Cu(H2O)2}2{Cu(H2O)4H4W12O42}]•12H2O

被引：9
|
作者：
Zhang, Chun-jing [1 ]
Chen, Ya-guang [1 ]
Shi, Dong-mei [1 ]
Pang, Hai-jun [1 ]
机构：
[1] NE Normal Univ, Coll Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Peoples R China
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2008年 / 63卷 / 02期
关键词：
polyoxometalates; transition metal bridge; 3D architecture; magnetic properties;
D O I：
10.1515/znb-2008-0212
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel transition metal polyoxotungstate, [Cu(H2O)(6)][{Cu(H2O)(2)}(2){Cu(H2O)(4)H4W12O42}]center dot 12H(2)O (1), has been synthesized in aqueous solution and characterized by single-crystal X-ray diffraction, elemental analysis, IR and UV/vis spectroscopy, and TG analysis. The paradode-catungstate anions [H2W12O42](10-) are linked by CuO6 octahedra, forming a three-dimensional (3D) structure. The magnetic susceptibility of compound I in the temperature range 2-300 K shows the presence of antiferromagnetic interactions within the uniform Cu2 center dot center dot center dot Cu3 chains.
引用
收藏
页码：187 / 192
页数：6
相关论文
共 50 条
  • [31] Crystal structures of acid ethylenediaminetetraacetates [Cd(H2Edta)(H2O)]•2H2O and [Mn(H2O)4][Mn(HEdta)(H2O)]2•4H2O
    Polyakova, IN
    Poznyak, AL
    Sergienko, VS
    Stopolyanskaya, LV
    [J]. CRYSTALLOGRAPHY REPORTS, 2001, 46 (01) : 40 - 45
  • [32] The water dimer reaction OH + (H2O)2 → (H2O)-OH + H2O
    Gao, Aifang
    Li, Guoliang
    Peng, Bin
    Xie, Yaoming
    Schaefer, Henry F., III
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2017, 19 (28) : 18279 - 18287
  • [33] Hydration of zinc ions:: theoretical study of [Zn(H2O)4](H2O)82+ and [Zn(H2O)6](H2O)62+
    Díaz, N
    Suárez, D
    Merz, KM
    [J]. CHEMICAL PHYSICS LETTERS, 2000, 326 (3-4) : 288 - 292
  • [34] Synthesis, Structure and Characterization of a New Complex: [Mn(C6H12N4)2(H2O)4][Mn(H2O)6][SO4]2·6H2O
    李登鹏
    许智煌
    叶李旺
    曹腾飞
    庄欣欣
    [J]. Chinese Journal of Structural Chemistry, 2021, 40 (09) : 1169 - 1176
  • [35] Synthesis, Structure and Antimicrobial Activity of a Cyclic Compound [Cu（Pmal）(Dadm)（H2O）]2·4H2O
    林郑忠
    陈素艳
    周常义
    张亚平
    赖注治
    陈静
    [J]. Chinese Journal of Structural Chemistry, 2013, (03) : 381 - 386
  • [36] Synthesis, Structure and Antimicrobial Activity of a Cyclic Compound [Cu(Pmal)(Dadm)(H2O)]2•4H2O
    Lin Zheng-Zhong
    Chen Su-Yan
    Zhou Chang-Yi
    Zhang Ya-Ping
    Lai Zhu-Zhi
    Chen Jing
    [J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2013, 32 (03) : 381 - 386
  • [37] Synthesis and Crystal Structure of a New Tetracopper Complex [Cu(H2O)3Cu(HCDTA)]2(ClO4)2·H2O
    王美香
    党振华
    徐立
    [J]. Chinese Journal of Structural Chemistry, 2010, 29 (04) : 551 - 554
  • [38] Synthesis and Crystal Structure of a New Tetracopper Complex [Cu(H2O)3Cu(HCDTA)]2(ClO4)2•H2O
    Wang Mei-Xiang
    Dang Zhen-Hua
    Xu Li
    [J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 29 (04) : 551 - 554
  • [39] SynthesisandCrystalStructureofaNovelThree-dimensionalCu（II）Compound{[Cu（2,2'-bipy）(C7H4O5S)（H2O）2]·H2O}_n
    SU Wei CAO Rong BI WenHua LI Xing State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian China
    [J]. 结构化学, 2005, (04) : 403 - 406+366
  • [40] Synthesis and Structure of 〔Cu（Hcdta）〕（H2O）
    YANG Xi-Ping
    CHEN Chang-Zhang
    SHAO Shi-Bao
    LIN Zhou-Bin
    GAO Dong-Shou(Fujian Institute of Research on the Structure of Matter
    [J]. Chinese Journal of Structural Chemistry, 1997, (03) : 211 - 214
12345