Fluorinated ketene dithioacetals.: Part 7:: New β-halo perfluorodithiocrotonic acid esters from perfluoroketene dithioacetals

被引：12
|
作者：
Bouillon, JP
Shermolovich, YG
Portella, C
机构：
[1] NAS Ukraine, Inst Organ Chem, UA-02094 Kiev, Ukraine
[2] Univ Reims, Fac Sci, CNRS, UMR 6519,Lab React Select & Applicat, F-51687 Reims 2, France
来源：
TETRAHEDRON LETTERS | 2001年 / 42卷 / 11期
关键词：
D O I：
10.1016/S0040-4039(01)00148-4
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Esters of beta -bromo or beta -chloro perfluorodithiocrotonic acid were prepared from corresponding ketenedithioacetal with anhydrous magnesium halides. These new polyfluorinated dithiocarboxylates are good dienophiles reacting selectively via the C=S bond. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2133 / 2135
页数：3
相关论文
共 26 条
  • [11] Oxidative cyclization based on reversing the polarity of enol ethers and ketene dithioacetals. Construction of a tetrahydrofuran ring and application to the synthesis of (+)-nemorensic acid
    Liu, B
    Duan, SQ
    Sutterer, AC
    Moeller, KD
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (34) : 10101 - 10111
  • [12] FLUORINATED KETENE DITHIOACETALS .1. PREPARATION AND APPLICATION TO THE SYNTHESIS OF ALPHA-TRIFLUOROMETHYLTHIOCARBOXYLIC S-ESTERS AND ALDEHYDE DERIVATIVES
    MUZARD, M
    PORTELLA, C
    SYNTHESIS-STUTTGART, 1992, (10): : 965 - 968
  • [13] SYNTHESIS OF ALPHA-PYRONES FROM VINYLOGOUS THIOL ESTERS AND ALPHA-OXO KETENE DITHIOACETALS
    DIETER, RK
    FISHPAUGH, JR
    JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (09): : 2031 - 2046
  • [14] Fluorinated ketene dithioacetals 6.: Synthesis of α-trifluoromethyl-γ-lactams from bis(ethylsulfanyl) (tetrafluoroethylidene)methane
    Hénin, B
    Huot, JF
    Portella, C
    JOURNAL OF FLUORINE CHEMISTRY, 2001, 107 (02) : 281 - 283
  • [15] Some reactions with ketene dithioacetals. Part III: Novel synthesis of pyrimidine, pyrazole and pyrazolo[3,4-d]pyrimidine derivatives as antimicrobial agents
    Ammar, YA
    Al-Sehemi, AG
    El-Gaby, MSA
    El-Sharief, AMS
    Zahran, MA
    El-Said, UH
    AFINIDAD, 2004, 61 (511) : 261 - 265
  • [16] POLARIZED KETENE DITHIOACETALS .28. A NEW GENERAL HIGHLY STEREOSELECTIVE AND REGIOSPECIFIC METHOD FOR HOMOLOGATION OF KETONES TO ALPHA,BETA-UNSATURATED ESTERS VIA ALPHA-OXOKETENE DITHIOACETALS
    MYRBOH, B
    ILA, H
    JUNJAPPA, H
    JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (26): : 5327 - 5332
  • [17] One-pot synthesis of substituted furans and pyrroles from propargylic dithioacetals. New annulation route to highly photoluminescent oligoaryls
    Lee, CF
    Yang, LM
    Hwu, TY
    Feng, AS
    Tseng, JC
    Luh, TY
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (20) : 4992 - 4993
  • [18] A NEW ROUTE TO 3H-1,5-BENZODIAZEPINES AND HETEROCYCLIC KETENE AMINALS FROM BENZOYL SUBSTITUTED KETENE DITHIOACETALS AND DIAMINES
    HUANG, ZT
    WANG, MX
    SYNTHESIS-STUTTGART, 1992, (12): : 1273 - 1276
  • [19] New Ketene Dithioacetals Generated from 2-Nitroperchlorobutadiene and Investigation of Their Antibacterial, Antifungal, Anticonvulsant and Antidepressant Activities
    Aydinli, Serdar Goksin
    Bulut, Elif
    Deniz, Nahide Gulsah
    Sayil, Cigdem
    Komarovska-Porokhnyavets, Olena
    Lubenets, Vira
    Zvarych, Viktor
    Stasevych, Maryna
    Nesterkina, Mariia
    Kravchenko, Iryna
    CHEMISTRY & BIODIVERSITY, 2022, 19 (07)
  • [20] PREPARATION OF PROTECTED BETA-KETO ALDEHYDES FROM BETA-KETO-ESTERS VIA SELECTIVE REDUCTION OF ACYL(ALKOXYCARBONYL)KETENE DITHIOACETALS
    CHOI, EB
    YOUN, IK
    PAK, CS
    SYNTHESIS-STUTTGART, 1988, (10): : 792 - 794
123