A promising NiCo2O4 protective coating for metallic interconnects of solid oxide fuel cells

被引：66
|
作者：
Hua, Bin [1 ]
Zhang, Wenying [1 ]
Wu, Juan [1 ]
Pu, Jian [1 ]
Chi, Bo [1 ]
Jian, Li [1 ]
机构：
[1] Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Mat Proc & Die & Mould Technol, Wuhan 430074, Hubei, Peoples R China
来源：
JOURNAL OF POWER SOURCES | 2010年 / 195卷 / 21期
基金：
中国国家自然科学基金; 国家高技术研究发展计划(863计划);
关键词：
Solid oxide fuel cell; Metallic interconnect; Coating; Spinel; Area specific resistance; FERRITIC STAINLESS-STEELS; OXIDATION BEHAVIOR; CHROMIUM VAPORIZATION; CATHODE; SPINEL; ALLOYS; ATMOSPHERE; LA;
D O I：
10.1016/j.jpowsour.2010.05.031
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The NiCo2O4 spinel coating is applied onto the surfaces of the SUS 430 ferritic stainless steel by the sol-gel process; and the coated alloy, together with the uncoated as a comparison, is cyclically oxidized in air at 800 degrees C for 200 h. The oxidation behavior and oxide scale microstructure as well as the electrical property are characterized. The results indicate that the oxidation resistance is significantly enhanced by the protective coating with a parabolic rate constant of 8.1 x 10(-15) g(2) cm(-4) s(-1), while the electrical conductivity is considerably improved due to inhibited growth of resistive Cr2O3 and the formation of conductive spinel phases in the oxide scale. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：7375 / 7379
页数：5
相关论文
共 50 条
  • [41] Recent advances in spinel-based protective coatings produced by electrochemical method on metallic interconnects for solid oxide fuel cells
    Zhu, Huimin
    Zhang, Jun
    Cao, Wenbo
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2024, 50 : 977 - 991
  • [42] Recent advances in spinel-based protective coatings produced by electrochemical method on metallic interconnects for solid oxide fuel cells
    Zhu, Huimin
    Zhang, Jun
    Cao, Wenbo
    International Journal of Hydrogen Energy, 2024, 50 : 977 - 991
  • [43] Sputtered MnCu metallic coating on ferritic stainless steel for solid oxide fuel cell interconnects application
    Geng, Shujiang
    Zhao, Qingqing
    Li, Yaohua
    Mu, Jianjia
    Chen, Gang
    Wang, Fuhui
    Zhu, Shenglong
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (15) : 10298 - 10307
  • [44] CHARACTERIZATION OF NICO2O4 ELECTRODES FOR O-2 EVOLUTION .2. NONELECTROCHEMICAL CHARACTERIZATION OF NICO2O4 ELECTRODES
    HAENEN, J
    VISSCHER, W
    BARENDRECHT, E
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1986, 208 (02): : 297 - 321
  • [45] Protective coating based on manganese-copper oxide for solid oxide fuel cell interconnects: Plasma spray coating and performance evaluation
    Waluyo, Nurhadi S.
    Park, Seong-Sik
    Song, Rak-Hyun
    Lee, Seung-Bok
    Lim, Tak-Hyoung
    Hong, Jong-Eun
    Ryu, Kwang Hyun
    Im, Won Bin
    Lee, Jong-Won
    CERAMICS INTERNATIONAL, 2018, 44 (10) : 11576 - 11581
  • [46] Microstructural and Electrical Characterization of Plasma Sprayed Cu-Mn Oxide Spinels as Coating on Metallic Interconnects for Stacking Solid Oxide Fuel Cells
    Spotorno, R.
    Piccardo, P.
    Perrozzi, F.
    Valente, S.
    Viviani, M.
    Ansar, A.
    FUEL CELLS, 2015, 15 (05) : 728 - 734
  • [47] Oxidation characteristics and electrical properties of La- or Ce-doped MnCo2O4 as protective layer on SUS441 for metallic interconnects in solid oxide fuel cells
    Tseng, Hui-Ping
    Yung, Tung-Yuan
    Liu, Chien-Kuo
    Cheng, Yung-Neng
    Lee, Ruey-Yi
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2020, 45 (22) : 12555 - 12564
  • [48] In-situ construction of NiCo2O4 nanoarrays on La0.8Sr0.2MnO3-δ electrodes for intermediate temperature solid oxide fuel cells
    Wentao Qi
    Haoshan Wei
    Yong Zhang
    Jiaqin Liu
    Qi Zhou
    Wenfang Wang
    Jiewu Cui
    Yan Wang
    Chuansheng Chen
    Yucheng Wu
    Journal of Solid State Electrochemistry, 2018, 22 : 2367 - 2374
  • [49] Nano-Oxide Dispersed Ferritic Stainless Steel for Metallic Interconnects of Solid Oxide Fuel Cells
    Mehran, Muhammad Taqi
    Song, Rak-Hyun
    Lee, Jung-Won
    Khan, Muhammad Zubair
    Lee, Seung-Bok
    Lee, Jong-Won
    Lim, Tak-Hyoung
    Hong, Jong-Eun
    Park, Seok-Joo
    SOLID OXIDE FUEL CELLS 15 (SOFC-XV), 2017, 78 (01): : 1575 - 1582
  • [50] In-situ construction of NiCo2O4 nanoarrays on La0.8Sr0.2MnO3-δ electrodes for intermediate temperature solid oxide fuel cells
    Qi, Wentao
    Wei, Haoshan
    Zhang, Yong
    Liu, Jiaqin
    Zhou, Qi
    Wang, Wenfang
    Cui, Jiewu
    Wang, Yan
    Chen, Chuansheng
    Wu, Yucheng
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2018, 22 (08) : 2367 - 2374
12345