Synthesis and crystal structure of a cyano-bridged bimetallic complex [La(betaine)2(H2O)6Fe(CN)6]•2H2O

被引：0
|
作者：
Liang, SH [1 ]
Che, YX [1 ]
Zheng, JM [1 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2005年 / 24卷 / 04期
关键词：
crystal structure; synthesis; cyano-bridged bimetallic complex; hydrogen bond;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title complex [La(betaine)(2)(H2O)(6)Fe(CN)(6)](.)2H(2)O (betaine = (CH3)(3)NCH2CO2) has been synthesized and characterized by X-ray single-crystal structure analysis. The crystal crystallizes in monoclinic, space group P2(1)/n with a = 15.793(5), b = 8.927(3), c = 22.257(7) A angstrom, P = 110. 147(5)degrees, C16H38FeLaN8O12, M-r.= 729.31, Z = 4, V = 2946.0(15) angstrom(3), D-c, = 1.640 g/m(3), mu(MoK alpha) = 1.988 mm(-1), F(000) = 1476, R = 0.0388 and wR = 0.0827. for 4237 observed reflections (I > 2(l)). The La3+ Ion is nine-coordinated by one cyano nitrogen atom and eight oxygen atoms of two betaine and six water molecules. Each complex molecule is connected to form a 3D network structure by some 0-H... 0 and 0-H... N hydrogen bonds.
引用
下载
收藏
页码：424 / 428
页数：5
相关论文
共 50 条
  • [41] Structure, ferromagnetic ordering, anisotropy, and spin reorientation for the two-dimensional cyano-bridged bimetallic compound K2Mn3(H2O)6[Mo(CN)7]2•6H2O
    Larionova, J
    Kahn, O
    Gohlen, S
    Ouahab, L
    Clérac, R
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (14) : 3349 - 3356
  • [42] CRYSTAL AND MOLECULAR-STRUCTURE STUDIES OF [CO(H2O)6[2+[CO(H2O)HEDTA](2)-.2H2O AND [CO(H2O)HEDTA].2H2O
    LOTT, S
    ZUBKOWSKI, JD
    VALENTE, EJ
    PERRY, DL
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 206 : 139 - INOR
  • [43] A Novel 3D Heterobimetallic Cyano-bridged Coordination Polymer {(NH4)2[Cd(H2O)Fe(CN)6]}n: Synthesis and Crystal Structure
    Qv Jing-Yan
    Mo Zong-Qiao
    Sun Ya-Qiu
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 33 (07) : 990 - 994
  • [44] CRYSTAL-STRUCTURE OF LA[FE(CN)6].5H2O AND SM[FE(CN)6].4H2O
    KIETAIBL, H
    PETTER, W
    HELVETICA PHYSICA ACTA, 1974, 47 (04): : 425 - 425
  • [45] Synthesis and structural characterisation of a cyano-bridged trinuclear complex [(CuL)2Fe(CN)6][ClO4]•2CH3OH•H2O
    Mondal, N
    Mitra, S
    Rosair, G
    POLYHEDRON, 2001, 20 (19) : 2473 - 2476
  • [46] Synthesis, Crystal Structure and Properties of the Cyano-bridged Heteropolynuclear [Cu(meso)]3[Co(CN)6]2•9.5H2O Compound
    Ishiruji, Fabiana H. O.
    Speziali, Nivaldo L.
    Vaz, Maria G. F.
    Nunes, Fabio S.
    JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2010, 21 (07) : 1195 - 1200
  • [47] Synthesis, Crystal Structure and Magnetic Property of a Cyano-Bridged Two-Dimensional Heterometallic Assembly [Mn(salen)]2[Fe(CN)5NO]·2H2O
    He-Qing Shu
    Yan Xu
    Xiao-Ping Shen
    Journal of Chemical Crystallography, 2011, 41 : 1218 - 1223
  • [48] Hydrothermal synthesis, crystal structure and characterization of [Zn(H2O)4]2 [H2As6V15O42(H2O)]•2H2O
    Cui, XB
    Xu, JQ
    Ding, L
    Ding, H
    Ye, L
    Yang, GY
    JOURNAL OF MOLECULAR STRUCTURE, 2003, 660 (1-3) : 131 - 137
  • [49] Synthesis, Crystal Structure and Magnetic Property of a Cyano-Bridged Two-Dimensional Heterometallic Assembly [Mn(salen)]2[Fe(CN)5NO]•2H2O
    Shu, He-Qing
    Xu, Yan
    Shen, Xiao-Ping
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2011, 41 (08) : 1218 - 1223
  • [50] Determination of the nuclear structure and spin density distribution in the cyano-bridged molecular based magnet K2Mn3(H2O)6[Mo(CN)7]2-6 H2O
    Stride, JA
    Gillon, B
    Goukassov, A
    Larionova, J
    Clérac, R
    Kahn, O
    COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE, 2001, 4 (02): : 105 - 112
12345