Synthesis and crystal structure of a cyano-bridged bimetallic complex [La(betaine)2(H2O)6Fe(CN)6]•2H2O

被引：0
|
作者：
Liang, SH [1 ]
Che, YX [1 ]
Zheng, JM [1 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2005年 / 24卷 / 04期
关键词：
crystal structure; synthesis; cyano-bridged bimetallic complex; hydrogen bond;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title complex [La(betaine)(2)(H2O)(6)Fe(CN)(6)](.)2H(2)O (betaine = (CH3)(3)NCH2CO2) has been synthesized and characterized by X-ray single-crystal structure analysis. The crystal crystallizes in monoclinic, space group P2(1)/n with a = 15.793(5), b = 8.927(3), c = 22.257(7) A angstrom, P = 110. 147(5)degrees, C16H38FeLaN8O12, M-r.= 729.31, Z = 4, V = 2946.0(15) angstrom(3), D-c, = 1.640 g/m(3), mu(MoK alpha) = 1.988 mm(-1), F(000) = 1476, R = 0.0388 and wR = 0.0827. for 4237 observed reflections (I > 2(l)). The La3+ Ion is nine-coordinated by one cyano nitrogen atom and eight oxygen atoms of two betaine and six water molecules. Each complex molecule is connected to form a 3D network structure by some 0-H... 0 and 0-H... N hydrogen bonds.
引用
收藏
页码：424 / 428
页数：5
相关论文
共 50 条
  • [1] Synthesis and Crystal Structure of a Cyano-bridged Bimetallic Complex[La（betaine）2（H2O）6Fe（CN）6]·2H2O
    LIANG Shu-Hui CHE Yun-Xia ZHENG Ji-Min② (Department of Chemistry
    [J]. Chinese Journal of Structural Chemistry, 2005, (04) : 424 - 428
  • [2] SynthesisandCrystalStructureofaCyano-bridgedBimetallicComplex[La（betaine）2（H2O）6Fe（CN）6]·2H2O
    LIANG ShuHui CHE YunXia ZHENG JiMin Department of Chemistry Nankai University Tianjin China
    [J]. 结构化学, 2005, (04) : 424 - 428+367
  • [3] Synthesis and Crystal Structure of a Cyano-bridged Bimetallic Complex:[NdFe（CN）6（DMF）4（H2O）3]H2O
    LI Jian-Ronga
    [J]. Chinese Journal of Structural Chemistry, 2003, (02) : 182 - 186
  • [4] Synthesis and crystal structure of a cyano-bridged bimetallic complex:: [NdFe(CN)6(DMF)4(H2O)3]•H2O
    Li, JR
    Guo, GC
    Wang, MS
    Zhou, GW
    Bu, XH
    Huang, JS
    [J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2003, 22 (02) : 182 - 186
  • [5] Synthesis and structure of a novel cyano-bridged compound SmFe(CN)6(DMSO)2•H2O
    Yang, C
    Guo, GC
    Ma, HW
    Liu, JC
    Zhang, X
    Zheng, FK
    Lin, SH
    Zhou, GW
    Mao, JG
    Huang, JS
    [J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2001, 20 (03) : 229 - 232
  • [6] Syntheses and Crystal Structures of Two Cyano-bridged Bimetallic Complexes [Ce（DMSO）4（H2O）3Fe（CN）6]·H2O and [La（DMSO）4（H2O）3Co（CN）6]·H2O（DMSO = Dimethylsulfoxide）
    赵振乾
    陈文通
    刘玺
    蔡丽珍
    郭国聪
    黄锦顺
    [J]. Chinese Journal of Structural Chemistry, 2006, (12) : 1481 - 1486
  • [7] Syntheses and crystal structures of two cyano-bridged bimetallic complexes [Ce(DMSO)4(H2O)3Fe(CN)6]•H2O and [La(DMSO)4(H2O)3Co(CN)6]•H2O (DMSO = dimethylsulfoxide)
    Zhao Zhen-Qian
    Chen Wen-Tong
    Liu Xi
    Cai Li-Zhen
    Guo Guo-Cong
    Huang Jin-Shun
    [J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2006, 25 (12) : 1481 - 1486
  • [8] The first cyano-bridged heptanuclear Mn(III)6Fe(III) cluster:: crystal structure and magnetic properties of [{Mn(salen)•H2O6Fe(CN)6][Fe(CN)6]•6H2O
    Shen, XP
    Li, BL
    Zou, JZ
    Hu, HM
    Xu, Z
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2003, 657 (1-3) : 325 - 331
  • [9] Synthesis and Crystal Structure of a Cyano-bridged Bimetallic Complex K3（TMS）2（H2O）2Cr（CN）6[TMS = Tetramethylene Sulfone]
    CHEN Wei CHE Yun-Xia② ZHENG Ji-Min (Department of Chemistry
    [J]. Chinese Journal of Structural Chemistry, 2005, (04) : 379 - 382
  • [10] Synthesis and crystal structure of a cyano-bridged bimetallic complex K3(TMS)2(H2O)2Cr(CN)6 [TMS = tetramethylene sulfone]
    Chen, W
    Che, YX
    Zheng, JM
    [J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (04) : 379 - 382
12345