Ir-Ru/Al2O3 catalysts used in satellite propulsion

被引:12
|
作者
Neto, TGS
Gobbo-Ferreira, J
Cobo, AJG
Cruz, GM
机构
[1] Inst Nacl Pesquisas Espaciais, Lab Associado Combustao & Propulsao, BR-12630000 Cachoeira Paulista, SP, Brazil
[2] Univ Estadual Campinas, Fac Engn Quim, BR-13083970 Campinas, SP, Brazil
[3] Fac Engn Quim Lorena, BR-12600000 Lorena, SP, Brazil
关键词
iridium catalyst; ruthenium catalyst; iridium-ruthenium bimetallic catalyst; hydrazine decomposition; spacecraft propulsion; textural properties; TEM; chloride influence;
D O I
10.1590/S0104-66322003000300007
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Ir/Al2O3, Ir-Ru/Al2O3 and Ru/Al2O3, catalysts with total metal contents of 30% were prepared using the methods of incipient wetness and incipient coimpregnation wetness and were tested in a 2N microthruster. Their performances were then compared with that of the Shell 405 commercial catalyst (30% Ir/Al2O3). Tests were performed in continuous and pulsed regimes, where there are steep temperature and pressure gradients, from ambient values up to 650 degreesC and 14 bar. Performance stability, thrust produced, temperature and stagnation pressure in the chamber and losses of mass were analyzed and compared to the corresponding parameters in Shell 405 tests. It was observed that the performance of all the above-mentioned catalysts was comparable to that of the commercial one, except for in loss of mass, where the values was higher, which was attributed to the lower mechanical resistance of the support.
引用
收藏
页码:273 / 282
页数:10
相关论文
共 50 条
  • [41] Comparative Studies of Bimetallic Ru–Cu, Rh–Cu, Ag–Cu, Ir–Cu Catalysts Supported on ZnO–Al2O3, ZrO2–Al2O3 Systems
    Pawel Mierczynski
    [J]. Catalysis Letters, 2016, 146 : 1825 - 1837
  • [42] Hydrogen production from 2-propanol over Pt/Al2O3 and Ru/Al2O3 catalysts in supercritical water
    Karakus, Yagmur
    Aynaci, Fatih
    Kipcak, Ekin
    Akgun, Mesut
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (18) : 7298 - 7306
  • [43] Performance comparison of Ir/CNF and Ir/Al2O3 catalysts in a 2 N hydrazine microthruster
    Ricardo Vieira
    Pierre Bernhardt
    Marc-Jacques Ledoux
    Cuong Pham-Huu
    [J]. Catalysis Letters, 2005, 99 : 177 - 180
  • [44] Performance comparison of Ir/CNF and Ir/Al2O3 catalysts in a 2 N hydrazine microthruster
    Vieira, R
    Bernhardt, P
    Ledoux, MJ
    Pham-Huu, C
    [J]. CATALYSIS LETTERS, 2005, 99 (3-4) : 177 - 180
  • [45] Macroporous Monolithic Pt/γ-Al2O3 and K–Pt/γ-Al2O3 Catalysts Used for Preferential Oxidation of CO
    Yuan Zhang
    Cun Yu Zhao
    Hao Liang
    Yuan Liu
    [J]. Catalysis Letters, 2009, 127 : 339 - 347
  • [46] Study of Ir/WO3/Al2O3 ring opening catalysts
    Park, Jie-Won
    Thomas, Karine
    van Gestel, Jacob
    Gilson, Jean-Pierre
    Collet, Christine
    Dath, Jean-Pierre
    Houalla, Marwan
    [J]. APPLIED CATALYSIS A-GENERAL, 2010, 388 (1-2) : 37 - 44
  • [47] Selective Mo-Ir/Al2O3 sulfide catalysts for hydrodenitrogenation
    Cinibulk, J
    Vít, Z
    [J]. APPLIED CATALYSIS A-GENERAL, 2000, 204 (01) : 107 - 116
  • [48] TEMPERATURE - PROGRAMMED REDUCTION STUDY OF PT/IR/AL2O3 CATALYSTS
    WANG, XK
    SCHWARZ, JA
    [J]. APPLIED CATALYSIS, 1985, 18 (01): : 147 - 155
  • [49] Preparation of Mo/Al2O3 sulfide catalysts modified by Ir nanoparticles
    Cinibulk, J
    Vít, Z
    [J]. SCIENTIFIC BASES FOR THE PREPARATION OF HETEROGENEOUS CATALYSTS, 2002, 143 : 443 - 451
  • [50] THE ROLE OF TIN IN BIMETALLIC IR-SN/AL2O3 CATALYSTS
    FRETY, R
    BENAICHOUBA, B
    BUSSIERE, P
    CUNHA, DS
    LAM, YL
    [J]. JOURNAL OF MOLECULAR CATALYSIS, 1984, 25 (1-3): : 173 - 182