In Situ Observation of Gas Adsorption onto ZIF-8 Using Terahertz Waves

被引：21

作者：

Tanno, Takenori ^{[1
]}

Watanabe, Yutaro ^{[2
,5
]}

Umeno, Kyoko ^{[3
,6
]}

Matsuoka, Atsushi ^{[4
]}

Matsumura, Hirotoshi ^{[4
]}

Odaka, Masafumi ^{[4
]}

Ogawa, Nobuaki ^{[1
,4
]}

机构：

[1] Akita Univ, Ctr Reg Revitalizat Res & Educ, 1-1 Tegatagakuen Machi, Akita 0108502, Japan

[2] Akita Univ, Fac Engn & Resource Sci, 1-1 Tegatagakuen Machi, Akita 0108502, Japan

[3] Akita Univ, Grad Sch Engn & Resource Sci, 1-1 Tegatagakuen Machi, Akita 0108502, Japan

[4] Akita Univ, Grad Sch Engn Sci, 1-1 Tegatagakuen Machi, Akita 0108502, Japan

[5] MC Food Specialties Inc, Tokyo, Japan

[6] Akita Prefectural Ctr Analyt Chem, Akita, Japan

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2017年 / 121卷 / 33期

关键词：

ZEOLITIC IMIDAZOLATE FRAMEWORKS; SEMICONDUCTOR RAMAN LASER; SEPARATION; SIMULATIONS; FLEXIBILITY; SPECTROSCOPY; GENERATION; PROPANE; SPECTRA;

D O I：

10.1021/acs.jpcc.7b04833

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The adsorption behavior of energy-related gases onto ZIF-8 was investigated using terahertz waves. Comparison of the terahertz transmission spectra of ZIF-8 before and after exposure to the gases revealed that the 2 THz vibrational mode was involved in the gate-opening motion of organic linker molecules. The adsorption properties of each gas were detailed by monitoring the intensities of the 2 THz absorption peak.

引用

页码：17921 / 17924

页数：4

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