Complexes of lanthanide(III) ions with 18-membered Schiff-base macrocycles

被引：10
|
作者：
Platas, C
Bastida, R
de Blas, A
Fenton, DE
Macias, A
Rodriguez, A
Rodriguez-Blas, T
机构：
[1] Univ A Coruna, Dept Quim Fundamental & Ind, La Coruna 15071, Spain
[2] Univ Santiago de Compostela, Dept Quim Inorgan, Santiago De Compostela 15706, Spain
[3] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England
来源：
POLYHEDRON | 1998年 / 17卷 / 10期
关键词：
template synthesis; lanthanide(III) complexes; polyoxaazamacrocycle; Schiff-base; ion-selectivity;
D O I：
10.1016/S0277-5387(97)00429-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
18-membered hexadentate N4O2 and N3O3 Schiff-base polyoxaazamacrocycles derived from 2,6-bis(2-aminophenoxymethyl) pyridine and different organic dicarbonyl compounds are obtained by a template procedure as mononuclear lanthanide(III) complexes. In the absence of the metal salt, macrocycles are not formed. The complexes were characterised by elemental analysis, molar conductivity and mass, UV-V, IR, H-1 NMR and C-13 NMR spectroscopy. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1759 / 1765
页数：7
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