Study on thermochemistry and thermal decomposition kinetics of Dy(Tyr)(Gly)3Cl3•3H2O

被引：1
|
作者：
Zhang, ZH [1 ]
Ku, ZJ
Liu, Y
Qu, SS
机构：
[1] Xiaogan Univ, Dept Chem, Xiaogan 432000, Hubei, Peoples R China
[2] Wuhan Univ, Coll Chem & Mol Sci, Dept Chem Biol, Wuhan 430072, Hubei, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2005年 / 23卷 / 09期
关键词：
complex of rare earths; amino acid; standard enthalpy of formation; thermal analysis kinetics;
D O I：
10.1002/cjoc.200591146
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The complex of dysprosium chloride with glycine and L-tyrosine, Dy(Tyr)(Gly)(3)Cl(3)(.)3H(2)O, was synthesized and characterized. The standard molar formation enthalpy of Dy(Tyr)(Gly)(3)Cl(3)(.)3H(2)O at T=298.15 K was determined to be (-4287.10 +/- 2.14) kJ/mol. The kinetics of thermal decomposition of the complex was studied by non-isothermal TG-DTG curves. The kinetic parameters and mechanism function of the thermal decomposition reaction for its second step were proposed. The kinetic equation could be expressed as: da/dT=3.14 X 10(20) S-1/,beta exp(- 209.37 kJ(.)mol(.1)/RT)(1 -alpha)(2).
引用
收藏
页码：1146 / 1150
页数：5
相关论文
共 50 条
  • [41] THERMAL DEHYDRATION OF CeP3O9•3H2O BY CONTROLLED RATE THERMAL ANALYSIS
    Nahdi, K.
    Ferid, M.
    Ayadi, Malika Trabelsi
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2009, 96 (02) : 455 - 461
  • [42] 氯化钐与甘氨酸配合物Sm（Gly）2Cl3·3H2O热化学研究
    卢基林
    刘北平
    谭志诚
    张大顺
    陈远道
    李琳
    无机化学学报, 2007, (09) : 1639 - 1643
  • [43] CRYSTAL STRUCTURE OF TRINUCLEAR MOLYBDENUM CLUSTER H(Mo3O（OAc）3Cl6)·3H2O
    Lin Chichang Chen GongDepartment of Chemistry
    结构化学, 1986, (01) : 10 - 13
  • [44] STUDY OF METHANEDISULFONIC ACID COMPOUNDS - CRYSTALLINE-STRUCTURE AND THERMAL-BEHAVIOR OF CA(SO3CH2SO3), 3H2O AND CD(SO3CH2SO3), 3H2O
    CHARBONNIER, F
    FAURE, R
    LOISELEUR, H
    REVUE DE CHIMIE MINERALE, 1979, 16 (06): : 555 - 564
  • [45] Kinetics of Thermal Decomposition for Complex [Zn(C16H18FN3O3)2(NO3)2]·2H2O
    张建军
    戴玉杰
    Rare Metals, 2000, (04) : 285 - 289
  • [46] Standard enthalpies of formation of [Ln(Gly)3(H2O)2]Cl3•2H2O (Ln = Pr, Nd; Gly = glycine):: A calorimetric study
    Yu, HG
    Dong, JX
    Liu, Y
    Qu, SS
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2003, 48 (05): : 1279 - 1282
  • [47] Kinetics of thermal decomposition for complex [Zn(C16H18FN3O3)2(NO3)2]•2H2O
    Zhang, JJ
    Dai, YJ
    RARE METALS, 2000, 19 (04) : 285 - 289
  • [48] Study of reaction of fluoride-ion substitution in [PtF 3Cl3]/2(-)
    Levchenko, L.M.
    Shipachev, V.A.
    Tkachev, S.V.
    Koordinatsionnaya Khimiya, 1992, 18 (12):
  • [49] Synthesis　and　Structureof［（C2H5）4N］［Mo3（μ3－O）(μ－Cl)3（μ－CH3CH2COO）3Cl3］
    Zhuang Hong-Hui
    Wu Ding-Ming
    Huang Jian-Quan
    Huang Jin-Ling(State Key Laboratory of Structural Chemistry and Fujitan Institute of Research on the Structure of Matter
    结构化学, 1996, (04) : 257 - 260
  • [50] Synthesis and Crystal Structure of[Fe2V （μ3-O） （μ-O2CCH3）6 （THF）3]Cl· 3H2O
    ZHOU Wen-Bo
    CUI Yong
    ZHANG Lin-Na
    HE Ling-Jie
    CAI Su-Hua
    CHEN Bo(Fujian Institute of Research on the Structure of Matter
    结构化学, 1998, (05) : 341 - 344
12345