A polymeric copper(II) complex bridged by benzene-1,3,5-tricarboxylate

被引:9
|
作者
Wei, WY [1 ]
Han, JY [1 ]
机构
[1] Tianjin Univ, Key Lab Green Chem Technol, State Educ Minist, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
关键词
D O I
10.1107/S1600536805025687
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The asymmetric unit of the title polymer, poly[copper(II)-mu(6)-benzene-1,3,5-tricarboxylato-tri-mu 3-hydroxo], [Cu-3(C9H3O6)(OH)(3)](n), contains two independent Cu-II atoms, one located in a general position assuming a pyramidal coordination geometry, and the other located on an inversion center assuming a square-planar geometry. The benzenetricarboxylate and hydroxo groups bridge the Cu-II atoms to form a three-dimensional polymeric structure.
引用
下载
收藏
页码:M1792 / M1793
页数:2
相关论文
共 50 条
  • [21] Benzene-1,3,5-tricarboxylate-bridged double-layered nickel(II) complex with ferromagnetically coupled Ni3 units
    Yang Hui-Juan
    Cui Ai-Li
    Wang Ru-Ji
    Kou Hui-Zhong
    CHINESE JOURNAL OF CHEMISTRY, 2008, 26 (08) : 1527 - 1531
  • [22] Synthesis and structure of tris(triphenyltin)benzene-1,3,5-tricarboxylate and its tri-DMSO adduct
    Dakternieks, D
    Clarke, DJ
    Tiekink, ERT
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2002, 217 (11): : 622 - 626
  • [23] Adsorption and photoactivity performances of copper(II)-benzene-1,3,5-tricarboxylate (Cu-BTC) and zeolitic imidazolate framework (ZIF-8): effect of humidity
    Tuncel, Duygu
    Okte, A. Neren
    JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2023, 98 (12) : 2925 - 2942
  • [24] Synthesis, crystal structure, and physicochemical properties of the new metal-organic framework - the iron(III) complex with benzene-1,3,5-tricarboxylate
    Sotnik, S. A.
    Kolotilov, S. V.
    Kiskin, M. A.
    Dobrokhotova, Zh. V.
    Gavrilenko, K. S.
    Novotortsev, V. M.
    Eremenko, I. L.
    Imshennik, V. K.
    Maksimov, Yu. V.
    Pavlishchuk, V. V.
    RUSSIAN CHEMICAL BULLETIN, 2014, 63 (04) : 862 - 869
  • [25] Catalysis by Dynamically Formed Defects in a Metal-Organic Framework Structure: Knoevenagel Reaction Catalyzed by Copper Benzene-1,3,5-tricarboxylate
    Polozij, Miroslav
    Rubes, Miroslav
    Cejka, Jiri
    Nachtigall, Petr
    CHEMCATCHEM, 2014, 6 (10) : 2821 - 2824
  • [26] Investigating the influence of copper benzene-1,2-dicarboxylate (Cu-BDC) and benzene-1,3,5-tricarboxylate ligands (Cu-BTC) on the electrochemical capacity of hybrid supercapacitors
    Shoukat W.
    Iqbal M.Z.
    Khizar A.
    Murtaza I.
    Alam S.
    Ali R.
    Wabaidur S.M.
    Faisal M.M.
    Current Applied Physics, 2024, 64 : 40 - 47
  • [27] Mixed Matrix Membranes of Pebax1657 Loaded With Iron Benzene-1,3,5-Tricarboxylate for Gas Separation
    Mosleh, Samira
    Mozdianfard, Mohammadreza
    Hemmati, Mahmood
    Khanbabaei, Ghader
    POLYMER COMPOSITES, 2017, 38 (07) : 1363 - 1370
  • [28] Synthesis, crystal structure, and physicochemical properties of the new metal-organic framework — the iron(iii) complex with benzene-1,3,5-tricarboxylate
    S. A. Sotnik
    S. V. Kolotilov
    M. A. Kiskin
    Zh. V. Dobrokhotova
    K. S. Gavrilenko
    V. M. Novotortsev
    I. L. Eremenko
    V. K. Imshennik
    Yu. V. Maksimov
    V. V. Pavlishchuk
    Russian Chemical Bulletin, 2014, 63 : 862 - 869
  • [29] Facile shape-controlled synthesis of luminescent europium benzene-1,3,5-tricarboxylate architectures at room temperature
    Liu, Kai
    You, Hongpeng
    Zheng, Yuhua
    Jia, Guang
    Zhang, Lihui
    Huang, Yeju
    Yang, Mei
    Song, Yanhua
    Zhang, Hongjie
    CRYSTENGCOMM, 2009, 11 (12): : 2622 - 2628
  • [30] Experimental and numerical study of CO2 adsorption on copper benzene-1,3,5-tricarboxylate (Cu-BTC) metal organic framework
    Wang, H.
    Qu, Z. G.
    Zhang, W.
    Yu, Q. N.
    He, Y. L.
    INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2016, 92 : 859 - 863