The effect of chain architecture of in situ formed copolymers on interfacial morphology of reactive polymer blends

被引：26
|
作者：
Kim, HY
Ryu, DY
Jeong, U
Kho, DH
Kim, JK [1 ]
机构：
[1] Pohang Univ Sci & Technol, Dept Chem Engn, Natl Creat Res Ctr Block Copolymer Self Assembly, Kyungbuk 790784, South Korea
[2] Pohang Univ Sci & Technol, Div Elect & Comp Engn, Polymer Res Inst, Kyungbuk 790784, South Korea
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2005年 / 26卷 / 17期
关键词：
chain architecture; interface morphology; microemulsion; reactive blend;
D O I：
10.1002/marc.200500219
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The effect of chain architecture of in situ formed copolymers on the interfacial morphology of reactive polymer blends was' investigated. We found that the chain architectures of copolymers at the interface significantly affected the reaction and interface roughness. Although the amount of in situ formed Y-shaped graft copolymers was smaller than that for diblock copolymers, the interface area generated by the former was larger than that generated by the latter.
引用
收藏
页码：1428 / 1433
页数：6
相关论文
共 50 条
  • [41] Morphology Development and Interfacial Erosion in Reactive Polymer Blending
    Bhadane, Prashant A.
    Tsou, Andy H.
    Cheng, John
    Favis, Basil D.
    MACROMOLECULES, 2008, 41 (20) : 7549 - 7559
  • [42] Interfacial Tension in Binary Polymer Blends and the Effects of Copolymers as Emulsifying Agents
    Anastasiadis, Spiros H.
    POLYMER THERMODYNAMICS: LIQUID POLYMER-CONTAINING MIXTURES, 2011, 238 : 179 - 269
  • [43] Compatibilization of immiscible polymer blends by reactive polymer grafted graphene with interfacial crosslinking
    Gavgani, Jaber Nasrollah
    Goharpey, Fatemeh
    JOURNAL OF APPLIED POLYMER SCIENCE, 2023, 140 (36)
  • [44] Morphology control of ternary polymer blends using interfacial tension
    Lee, MH
    Tzoganakis, C
    Kim, JM
    ANTEC 2000: SOCIETY OF PLASTICS ENGINEERS TECHNICAL PAPERS, CONFERENCE PROCEEDINGS, VOLS I-III, 2000, : 2438 - 2442
  • [45] Effect of molecular structure of PEG/PCL multiblock copolymers on the morphology and interfacial properties of PLA/PCL blends
    Lucas Henrique Staffa
    An-Sofie Huysecom
    Sílvia Helena Prado Bettini
    Paula Moldenaers
    Marcelo Aparecido Chinelatto
    Journal of Polymer Research, 2022, 29
  • [46] Effect of molecular structure of PEG/PCL multiblock copolymers on the morphology and interfacial properties of PLA/PCL blends
    Staffa, Lucas Henrique
    Huysecom, An-Sofie
    Prado Bettini, Silvia Helena
    Moldenaers, Paula
    Chinelatto, Marcelo Aparecido
    JOURNAL OF POLYMER RESEARCH, 2022, 29 (09)
  • [47] IN-SITU COMPATIBILIZATION OF PET/PS BLENDS THROUGH REACTIVE COPOLYMERS
    MAA, CT
    CHANG, FC
    JOURNAL OF APPLIED POLYMER SCIENCE, 1993, 49 (05) : 913 - 924
  • [48] IN-SITU COMPATIBILIZATION OF PBT/ABS BLENDS THROUGH REACTIVE COPOLYMERS
    LEE, PC
    KUO, WF
    CHANG, FC
    POLYMER, 1994, 35 (26) : 5641 - 5650
  • [49] Interfacial tension in binary polymer blends in the presence of block copolymers. 2. Effects of additive architecture and composition
    Retsos, H
    Anastasiadis, SH
    Pispas, S
    Mays, JW
    Hadjichristidis, N
    MACROMOLECULES, 2004, 37 (02) : 524 - 537
  • [50] Relationship between the Co-Continuous Morphology of Immiscible Polymer Blends and the Structure of an In Situ Formed Graft Copolymer
    Liang, Tianqi
    Huang, Qiwen
    Wei, Zhaoyang
    Lei, Weiwei
    You, Jun
    Liu, Jie
    Ren, Xiaoming
    Zhang, Qunchao
    Hu, Guohua
    Shi, Dean
    MACROMOLECULAR RAPID COMMUNICATIONS, 2023, 44 (15)
12345