The effect of chain architecture of in situ formed copolymers on interfacial morphology of reactive polymer blends

被引:26
|
作者
Kim, HY
Ryu, DY
Jeong, U
Kho, DH
Kim, JK [1 ]
机构
[1] Pohang Univ Sci & Technol, Dept Chem Engn, Natl Creat Res Ctr Block Copolymer Self Assembly, Kyungbuk 790784, South Korea
[2] Pohang Univ Sci & Technol, Div Elect & Comp Engn, Polymer Res Inst, Kyungbuk 790784, South Korea
关键词
chain architecture; interface morphology; microemulsion; reactive blend;
D O I
10.1002/marc.200500219
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The effect of chain architecture of in situ formed copolymers on the interfacial morphology of reactive polymer blends was' investigated. We found that the chain architectures of copolymers at the interface significantly affected the reaction and interface roughness. Although the amount of in situ formed Y-shaped graft copolymers was smaller than that for diblock copolymers, the interface area generated by the former was larger than that generated by the latter.
引用
收藏
页码:1428 / 1433
页数:6
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