Intermolecular radical carboaminohydroxylation of olefins with aryl diazonium salts and TEMPO

被引：97
|
作者：
Heinrich, Markus R. [1 ]
Wetzel, Alexander [1 ]
Kirschstein, Marcel [1 ]
机构：
[1] Tech Univ Munich, Lehrstuhl Organ Chem 1, D-85747 Garching, Germany
来源：
ORGANIC LETTERS | 2007年 / 9卷 / 19期
关键词：
D O I：
10.1021/ol701622d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Highly reactive aryl radicals can selectively be reacted with a broad variety of activated and nonactivated olefinic substrates in the presence of nitroxyl radicals. Direct recombination of the aryl radical and the nitroxide as well as telomerization of the olefin is successfully suppressed by the reaction conditions.
引用
收藏
页码：3833 / 3835
页数：3
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