Mono layer Adsorption Behavior of Hydrogen Isotopes on Microporous and Mesoporous Molecular Sieves

被引：10
|
作者：
Chu, Xiao-Zhong [1 ]
Xu, Ji-Ming [1 ]
Zhao, Yi-Jiang [1 ]
Zhang, Wei-Guang [1 ]
Chen, Zhi-Peng [1 ]
Zhou, Shou-Yong [1 ]
Zhou, Ya-Ping [2 ]
Zhou, Li [2 ]
机构：
[1] Huaiyin Normal Univ, Jiangsu Key Lab Chem Low Dimens Mat, Sch Chem & Chem Engn, Huaian 223300, Peoples R China
[2] Tianjin Univ, High Pressure Adsorpt Lab, State Key Lab Chem Engn, Tianjin 300072, Peoples R China
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2010年 / 55卷 / 07期
关键词：
PHYSISORPTION; CARBON;
D O I：
10.1021/je9008798
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The equilibrium adsorption amounts of hydrogen isotope gas and the Brunauer-Emmett-Teller (BET) surface area were measured at 77 K with different microporous and mesoporous molecular sieves. The results indicate that good linear relationships are observed between the amount adsorbed and the BET surface area at (0.02, 0.04 0.06, 0.08, 0.10, and 0.12) MPa for microporous or mesoporous adsorbents, which provide proof of the monolayer adsorption mechanism for hydrogen isotopes at supercritical temperatures. Effects of specific surface area and pore size are more important than the surface properties of adsorbents for hydrogen isotope storage with the physical adsorption method. The equilibrium adsorption difference between hydrogen and deuterium is increased with a decrease of pressure. Moreover, the adsorption capacity of hydrogen isotopes on mesoporous molecular sieves is smaller than that on microporous molecular sieves at the same temperature, pressure, and BET surface area.
引用
收藏
页码：2512 / 2516
页数：5
相关论文
共 50 条
  • [31] Adsorption of L-histidine over mesoporous carbon molecular sieves
    Vinu, A
    Hossain, KZ
    Kumar, GS
    Ariga, K
    [J]. CARBON, 2006, 44 (03) : 530 - 536
  • [32] Adsorption methods for characterization of surface and structural properties of mesoporous molecular sieves
    Jaroniec, M
    Kruk, M
    Sayari, A
    [J]. MESOPOROUS MOLECULAR SIEVES 1998, 1998, 117 : 325 - 332
  • [33] MOLECULAR OR SUPRAMOLECULAR TEMPLATING - DEFINING THE ROLE OF SURFACTANT CHEMISTRY IN THE FORMATION OF MICROPOROUS AND MESOPOROUS MOLECULAR-SIEVES
    BECK, JS
    VARTULI, JC
    KENNEDY, GJ
    KRESGE, CT
    ROTH, WJ
    SCHRAMM, SE
    [J]. CHEMISTRY OF MATERIALS, 1994, 6 (10) : 1816 - 1821
  • [34] Water Adsorption and Desorption Isotherms of Silica and Alumina Mesoporous Molecular Sieves
    Komarneni, Sridhar
    Pidugu, Rajyalakshmi
    Menon, Vinayan C.
    [J]. JOURNAL OF POROUS MATERIALS, 1996, 3 (02) : 99 - 106
  • [35] GAS-CHROMATOGRAPHIC SEPARATION OF HYDROGEN ISOTOPES ON MOLECULAR-SIEVES
    VOGD, R
    RINGEL, H
    HACKFORT, H
    SCHOBER, T
    DIEKER, C
    [J]. FUSION TECHNOLOGY, 1988, 14 (02): : 574 - 578
  • [36] Nickel dispersed microporous and mesoporous templated carbons for atmospheric hydrogen adsorption
    Konwar, Ruhit Jyoti
    Singh, Sohan Bir
    De, Mahuya
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 2024, 322
  • [37] Probing pore structure of microporous and mesoporous molecular sieves by quasi-equilibrated temperature programmed desorption and adsorption of n-nonane
    Makowski, Waclaw
    Kustrowski, Piotr
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2007, 102 (1-3) : 283 - 289
  • [38] Structural elucidation of microporous and mesoporous catalysts and molecular sieves by high-resolution electron microscopy
    Thomas, JM
    Terasaki, O
    Gai, PL
    Zhou, WZ
    Gonzalez-Calbet, J
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (07) : 583 - 594
  • [39] Characterization and microporosity analysis of mesoporous carbon molecular sieves by nitrogen and organics adsorption
    Vinu, A
    Hartmann, M
    [J]. CATALYSIS TODAY, 2005, 102 : 189 - 196
  • [40] Characterization of mesoporous molecular sieves containing copper and zinc: An adsorption and TPR study
    Hartmann, M
    [J]. CHARACTERIZATION OF POROUS SOLIDS V, 2000, 128 : 215 - 224
12345