Overlap concentration of an aqueous poly(N-vinylcaprolactam) solution in the dynamic and static states

被引：6
|
作者：
Foroutan, Masoumeh [1 ]
Khoee, Sepideh [2 ]
Zarrabi, Mona [1 ]
机构：
[1] Univ Tehran, Coll Sci, Fac Chem, Dept Phys Chem, Tehran, Iran
[2] Univ Tehran, Coll Sci, Fac Chem, Dept Polymer Chem, Tehran, Iran
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2008年 / 109卷 / 01期
关键词：
molding; phase behavior; refractive index; viscosity; water-soluble polymers;
D O I：
10.1002/app.27935
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The overlap concentration of poly(N-vinylcaprolactam)s (PVCLs) of low molecular weights was studied with dynamic and static methods (with viscosity and refractive-index measurements) at three temperatures (25, 30, and 35 degrees C). This concentration, determined by viscometry, was lower than the overlap concentration determined by refractometry. Also, the influence of the temperature and molecular weight on the viscosity and refractive index was investigated, and the opposite effect of the temperature on the viscosity and refractive index of PVCL solutions was observed. The experimental overlap concentration values were compared with those calculated with the Rao, Huggins, and Fuoss equations. The results showed that the Huggins equation is the best equation to describe the dilute solution properties of this polymer. (c) 2008 Wiley Periodicals, Inc.
引用
收藏
页码：597 / 601
页数：5
相关论文
共 50 条
  • [31] Aqueous solution behavior of thermoresponsive polyzwitterionic microgels based on poly(N-vinylcaprolactam) synthesized via RAFT precipitation polymerization
    Saha, Pabitra
    Kather, Michael
    Banerjee, Sovan L.
    Singha, Nikhil K.
    Pich, Andrij
    EUROPEAN POLYMER JOURNAL, 2019, 118 : 195 - 204
  • [32] Thermo-sensitive amphiphilic poly(N-vinylcaprolactam) copolymers: synthesis and solution properties
    Zhang, Lifen
    Liang, Yong
    Meng, Lingzhi
    POLYMERS FOR ADVANCED TECHNOLOGIES, 2010, 21 (10) : 720 - 725
  • [33] Effects of Different Stimuli on the Structure of Nano-Anatase and Poly(N-vinylcaprolactam) in the Nano-Anatase/Poly(N-vinylcaprolactam) Composites
    Timaeva, Olesya
    Chernyshev, Vladimir
    Kuz'micheva, Galina
    Ivanovskaya, Natalia
    Chikhacheva, Irina
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2019, 19 (12) : 7624 - 7634
  • [34] Development of thermosensitive poly(N-vinylcaprolactam) as an injectable biomaterial
    Sala, Renata
    Kwon, Michelle
    Camargo, Emerson
    Burdick, Jason
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 252
  • [35] Grafting of Poly(N-Vinylcaprolactam) in polyurethane by gamma radiation
    Cerqueira, Grazielle Rozendo de
    Feitosa, Rhodivam Lucas Mendes
    Henrique, Mariana Alves
    Andrade, Michele Félix
    Trindade, Felipe Cunha da Silva
    Araujo, Elmo Silvano
    Junior, Wilson Barros
    Navarro-Vázquez, Armando
    Vinhas, Glória Maria
    Almeida, Yêda Medeiros Bastos de
    Morelli, Carolina Lipparelli
    Radiation Physics and Chemistry, 2024, 217
  • [36] Intrinsic viscosity of poly(N-vinylcaprolactam) with varying the architecture
    Norma Aidé Cortez-Lemus
    Ana Castro-Hernández
    Journal of Polymer Research, 2020, 27
  • [37] Intrinsic viscosity of poly(N-vinylcaprolactam) with varying the architecture
    Cortez-Lemus, Norma Aide
    Castro-Hernandez, Ana
    JOURNAL OF POLYMER RESEARCH, 2020, 27 (08)
  • [38] Interaction between surfactant and poly(N-vinylcaprolactam) microgels
    Department of Chemistry, Chinese University of Hong Kong, Shatin, N. T., Hong Kong
    Macromolecules, 11 (3674-3677):
  • [39] On the thermodynamic phase behavior of poly(N-vinylcaprolactam) solution in the presence of different ionic liquids
    Li, Wenlong
    Wu, Peiyi
    POLYMER CHEMISTRY, 2014, 5 (03) : 761 - 770
  • [40] Poly(N-vinylcaprolactam) microgels and its related composites
    Peng, SF
    Wu, C
    MACROMOLECULAR SYMPOSIA, 2000, 159 : 179 - 186
12345