Synthesis and Characterization of [2+2] Cu(II) Macrocyclic Schiff Base Complexes

被引：0

作者：

Golbedaghi, Reza ^{[1
]}

Soudmand, Mehdi ^{[2
]}

Keymanesh, Mahmoud Reza ^{[3
]}

Veisi, Hojat ^{[1
]}

Azadbakht, Reza ^{[1
]}

Jaleh, Babak ^{[1
]}

机构：

[1] Payame Noor Univ, Dept Chem, Tehran 193954697, Iran

[2] Payame Noor Univ, Dept Phys, Tehran 193954697, Iran

[3] Payame Noor Univ, Dept Construct Engn Managment, Tehran 193954697, Iran

来源：

ASIAN JOURNAL OF CHEMISTRY | 2011年 / 23卷 / 09期

关键词：

Cyclocondensation; Tripodal; Macrocyclic complex; METAL-COMPLEXES; LIGANDS;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[2+2]Cyclocondensation of L(22py) = N-(2-pyridylmethyl)-N-(2-aminoethyl)-1,2-diaminoethane, L(23py) = N-(2-pyridylmethyl)-N-(2-aminoethyl)-1,3-diaminopropane, L(33py) = N-(2-pyridylmethyl)-N-(3-aminopropyl)-1,3-diaminopropane} and 2,6-diformyl-4-methylphenol (dfp), in the presence of Cu(ClO(4))(2)center dot 4H(2)O in equimolar ratios gave three new binuclear Cu(II) macrocyclic complexes. Resulting compounds, [{Cu(H(2)L(1))(H(2)O)}(2)](ClO(4))(4)(1), [{Cu(H(2)L(2))(H(2)O)}(2)](ClO(4))(4) (2) and [{Cu(H(2)L(3))(H(2)O)}(2)](ClO(4))(4)(3), were characterized by IR spectroscopy, elemental analysis and mass diffraction method. The Cu(II) ions in latter binuclear complex from penta-coordinated complexes.

引用

页码：4231 / 4232

页数：2

共 50 条

[41] Mn(II) complexes of three [2+2] macrocyclic Schiff base ligands. Synthesis and X-ray crystal structure of the first binuclear-di(binuclear) cocrystal
Golbedaghi, Reza
Salehzadeh, Sadegh
Khavasi, Hamid Reza
Blackman, Allan G.
[J]. POLYHEDRON, 2014, 68 : 151 - 156
[42] Manganese(II) Macrocyclic Schiff-Base Complexes Containing Pyridine Moiety: Synthesis and Characterization and Antibacterial Properties
Hassan, Keypour
Mozhdeh, Liyaghati-Delshad
Majid, Rezaeivala
Reza, Khavasi Hamid
[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2014, 30 (07) : 1733 - 1740
[43] Synthesis, Characterization and Biochemical Activity of Dinuclear Cu(II)/Ni(II)/Co(II) and Tetranuclear Cu(II) Complexes of Schiff Base
Karabocek, Nevin
Eski, Pinar
Baskan, Oya
Karabocek, Serdar
[J]. ASIAN JOURNAL OF CHEMISTRY, 2012, 24 (01) : 387 - 390
[44] Synthesis and characterization of a Ni(II) and Cu(I) complexes of Schiff base derived from salicylaldehyde
Demirhan, Nebahat
Karaoglan, Guelnur Keser
Aydin, Sezgin
[J]. ASIAN JOURNAL OF CHEMISTRY, 2008, 20 (03) : 2367 - 2372
[45] Synthesis and characterization of macrocyclic complexes of Co (II), Ni (II) and Cu (II)
Dilip, C. Surendra
Sivakumar, V.
Prince, J. Joseph
[J]. INDIAN JOURNAL OF CHEMICAL TECHNOLOGY, 2012, 19 (05) : 351 - 356
[46] Synthesis and Characterization of Schiff Base Ligands and Their Palladium(II) Complexes
El-Qisairi, Arab K.
Qaseer, Hanan A.
Al-Btoush, Wa'el
[J]. JORDAN JOURNAL OF CHEMISTRY, 2023, 18 (01) : 43 - 52
[47] Synthesis and characterization of some ruthenium(II) Schiff base complexes
Bhowon, MG
Nedhool, D
[J]. SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1999, 29 (04): : 607 - 620
[48] Synthesis, characterization, and antioxidant activities of three Cu(II) complexes with Schiff-base ligands
Wang, Yuan
Wu, Wei-Na
Wang, Qian
Yang, Zheng-Yin
[J]. JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (01) : 147 - 155
[49] Synthesis and crytal structure of Ni(II) and Cu(II) Schiff base complexes
Zhang Qi-Long
Dai Mei-Bi
Zhu Bi-Xue
[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2007, 23 (12) : 2018 - 2022
[50] Synthesis and characterization of N2S2-tin macrocyclic complexes of Co(II), Ni(II), Cu(II) and Zn(II)
Ghani, Syed Sauban
Deo, Aman
[J]. MAIN GROUP METAL CHEMISTRY, 2014, 37 (5-6) : 137 - 142

← 1 2 3 4 5 →