Urea assisted synthesis of TiO2-CeO2 composites for photocatalytic acetaminophen degradation via simplex-centroid mixture design

被引:13
|
作者
Garcia-Dominguez, Angel Emilio [1 ]
Torres-Torres, Gilberto [1 ]
Arevalo-Perez, Juan Carlos [1 ]
Silahua-Pavon, Adib [1 ]
Sanchez-Trinidad, Cecilia [1 ]
Godavarthi, Srinivas [2 ]
Ojeda-Lopez, Reyna [3 ]
Sierra-Gomez, Uriel Alejandro [4 ]
Cervantes-Uribe, Adrian [1 ]
机构
[1] Univ Juarez Autonoma Tabasco, Ctr Invest Ciencia & Tecnol Aplicada Tabasco CICTA, Lab Nanomat Catalit Aplicados Desarrollo Fuentes E, DACB, Km1 Carretera Cunduacan,Cunduacan,AP 24, Jalpa De Mendez 86690, Tabasco, Mexico
[2] Univ Juarez Autonoma Tabasco, Investigadoras Investigadores Mex Div Acad Ciencia, Cunduacan 86690, Tabasco, Mexico
[3] Univ Autonoma Metropolitana Iztapalapa, Dept Quim, Laboartorio Fisicoquim Superf, Ave San Rafael Atlixco 186, Col Vicentina, Ciudad, Ciudad de Mexico 09310, Mexico
[4] Ctr Invest Quim Aplicada, Enr Reyna H 140, San Jose Cerritos, Saltillo 25294, Coahuila, Mexico
关键词
TiO2; CeO2; Urea; Acetaminophem; Mixture design; N-DOPED TIO2; WASTE-WATER; CALCINATION TEMPERATURE; METHYLENE-BLUE; CODOPED TIO2; REMOVAL; UV; PHOTODEGRADATION; PARACETAMOL; OXIDATION;
D O I
10.1016/j.rineng.2022.100443
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We studied the effect of urea on TiO2-CeO2 and paracetamol photodegradation. The contribution of TiO2, CeO2, and urea was analyzed by simplex-centroid mixture. Solid-state combustion at 500 C was the method of synthesis. All samples were characterized by X-ray diffraction, nitrogen adsorption/desorption, Uv spectroscopy, and scanning electron spectroscopy (SEM). According to the results, urea influences particle morphology. Bandgap decreases due to interactions with residual urea carbon. The surface area depended on the crystallinity of the samples. The value of the kinetic constant increased as a function of the amount of urea. The selectivity to CO2 was the roll of cerium oxide.
引用
收藏
页数:14
相关论文
共 50 条
  • [41] High photocatalytic activity of rutile TiO2-BiOBr composites via an in situ synthesis approach
    Li, Xiangji
    Han, Bin
    Wang, Xiaofeng
    Bai, Peiming
    Sun, Leiming
    Hao, Qi
    Yu, Kaifeng
    Liang, Ce
    NEW JOURNAL OF CHEMISTRY, 2020, 44 (05) : 1905 - 1911
  • [42] Clinoptilolite supported rutile TiO2 composites: Synthesis, characterization, and photocatalytic activity on the degradation of terephthalic acid
    Yener, H. B.
    Yilmaz, M.
    Deliismail, O.
    Ozkan, S. F.
    Helvaci, S. S.
    SEPARATION AND PURIFICATION TECHNOLOGY, 2017, 173 : 17 - 26
  • [43] TiO2/ACTIVATED CARBON COMPOSITES FOR PHOTOCATALYTIC DEGRADATION OF ALIZARIN UNDER UV LIGHT - SYNTHESIS AND CHARACTERISATION
    Petrova, T.
    Eliyas, A.
    Kovacheva, D.
    Tsyntsarski, B.
    Velinov, N.
    JOURNAL OF ENVIRONMENTAL PROTECTION AND ECOLOGY, 2020, 21 (05): : 1577 - 1586
  • [44] Synthesis of new TiO2/porphyrin-based composites and photocatalytic studies on methylene blue degradation
    Min, Kyeong Su
    Kumar, Rangaraju Satish
    Lee, Jeong Hoon
    Kim, Kang Seok
    Lee, Seung Geol
    Son, Young-A
    DYES AND PIGMENTS, 2019, 160 : 37 - 47
  • [45] Rapid Microwave-Assisted Synthesis of N/TiO2/rGO Nanoparticles for the Photocatalytic Degradation of Pharmaceuticals
    Tobon, Camilo Sanchez
    Panzic, Ivana
    Bafti, Arijeta
    Matijasic, Gordana
    Ljubas, Davor
    Curkovic, Lidija
    NANOMATERIALS, 2022, 12 (22)
  • [46] Zeolite supported CdS/TiO2/CeO2 composite: Synthesis, characterization and photocatalytic activity for methylene blue dye degradation
    Mahamud, Mohammedsani
    Taddesse, Abi M.
    Bogale, Yiheyis
    Bezu, Zewdu
    MATERIALS RESEARCH BULLETIN, 2023, 161
  • [47] Improvement of the photocatalytic activity of CeO2 on the degradation of chlorophenolic compounds obtained by solution combustion synthesis (SCS). Effect of urea as fuel
    Aguilar-Martinez, Octavio
    Santolalla-Vargas, C. E.
    Tzompantzi, F.
    Gonzalez, Federico
    Romero-Ibarra, Issis Claudette
    de los Reyes, J. A.
    Arceo, Lucia Graciela Diaz-Barriga
    Santes, Victor
    SOLID STATE SCIENCES, 2023, 143
  • [48] Efficient Degradation of Gas-Phase Toluene by Ozone-Assisted Photocatalytic Oxidation on TiO2/Graphene Composites
    Ye, Haoling
    Wang, Zhi
    Liu, Yiqiu
    Chen, Si
    Wang, Haiqiang
    Wu, Zhongbiao
    CATALYSIS LETTERS, 2019, 149 (10) : 2739 - 2748
  • [49] Electric Field Assisted Femtosecond Laser Preparation of Au@TiO2 Composites with Controlled Morphology and Crystallinity for Photocatalytic Degradation
    Li, Xiaojie
    Li, Xin
    Zuo, Pei
    Chen, Xiaozhe
    Liang, Misheng
    Ma, Le
    MATERIALS, 2021, 14 (14)
  • [50] Efficient Degradation of Gas-Phase Toluene by Ozone-Assisted Photocatalytic Oxidation on TiO2/Graphene Composites
    Haoling Ye
    Zhi Wang
    Yiqiu Liu
    Si Chen
    Haiqiang Wang
    Zhongbiao Wu
    Catalysis Letters, 2019, 149 : 2739 - 2748