As(III) and As(V) adsorption on manganese ferrite nanoparticles

被引:72
|
作者
Martinez-Vargas, Sergio [1 ]
Martinez, Arturo I. [2 ]
Hernandez-Beteta, Elias E. [3 ]
Mijangos-Ricardez, Oscar F. [3 ]
Vazquez-Hipolito, Virgilio [4 ]
Patino-Carachure, Cristobal [1 ]
Lopez-Luna, Jaime [3 ]
机构
[1] Univ Autonoma Carmen, Fac Ingn, Campus III,Ave Cent S-N,Esq Con Fracc, Ciudad Del Carmen 24115, Campeche, Mexico
[2] Cinvestav Saltillo Ind, Zona Ind, Ramos Arizpe 25900, Coahuila, Mexico
[3] Univ Sierra Juarez, Inst Estudios Ambientales, Ixtlan De Juarez 68725, Oaxaca, Mexico
[4] Univ Tecnol Mixteca, Inst Fis & Matemat, Huajuapan De Leon 69000, Oaxaca, Mexico
关键词
Manganese ferrite nanoparticles; Arsenite; Arsenate; Pseudo-second order kinetics; Non-linear Freundlich isotherm model; OXIDE-MNFE2O4 MAGNETIC NANOHYBRIDS; ARSENATE ADSORPTION; EFFICIENT REMOVAL; NANO-ADSORBENTS; IONIC-STRENGTH; MNFE2O4; SORPTION; ARSENITE; BEHAVIOR; SINGLE;
D O I
10.1016/j.molstruc.2017.10.076
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The adsorption of As(III) and As(V) on manganese ferrite nanoparticles (NPs) was studied. The ferrite NPs were synthesized by co-precipitation and to know the amount of Mn in the ferrite NPs, EDX elemental analysis was performed. The SEM images of ferrite NPs show a size of similar to 50 nm and agglomerates of particles smaller than 20 nm were also distinguished. The main factors effecting arsenic adsorption optimization (ferrite dosage, pH and arsenic initial concentrations) were studied. Experimental data were fitted in agreement to the pseudo-second order kinetic model (PSO) and the Freundlich isotherm model. The manganese ferrite NPs confirmed high performance as arsenic adsorbent. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:524 / 534
页数:11
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