Reactions of 1,2,4,5-tetrafluoro-3,6-bis(vinylsulfonyl)benzene with nucleophilic reagents containing a mercapto group

被引:3
|
作者
Amosova, SV [1 ]
Gavrilova, GM [1 ]
Gostevskaya, VI [1 ]
机构
[1] Russian Acad Sci, Irkutsk Inst Chem, Siberian Div, Irkutsk 664033, Russia
关键词
Benzene; Organic Chemistry; Thiol; Title Compound; Thiol Group;
D O I
10.1023/A:1012333719217
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Addition of 2-aminoethanethiol and 2-mercaptocthanol at both vinylsulfonyl groups of 1,2,4,5-tetrafluoro-3,6-bis(vinyisulfonyl)benzene occurs through the thiol group of the reagent and yields the corresponding 3,6-dis[2-(2-aminoethylthio)ethylsulfonyl] and 3,6-bis[2-(2-hydroxyethylthio)ethylsulfonyl] derivatives. The reaction of the title compound with 1,2-ethanedithiol leads to formation of only polymeric addition products.
引用
收藏
页码:93 / 95
页数:3
相关论文
共 50 条
  • [21] OXIDATIONS OF 3,6-DIAMINO-1,2,4,5-TETRAZINE AND 3,6-BIS(S,S-DIMETHYLSULFILIMINO)-1,2,4,5-TETRAZINE
    COBURN, MD
    HISKEY, MA
    LEE, KY
    OTT, DG
    STINECIPHER, MM
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 1993, 30 (06) : 1593 - 1595
  • [22] Mesogenic 3,6-bis(4-hydroxyphenyl)-1,2,4,5-tetrazine alkanoate esters
    Fouad, Farid
    Khabouchi, Faycal
    Nielsen, Alek
    Twieg, Robert
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2018, 665 (01) : 82 - 90
  • [23] 2,2′:6′,2"-terpyridine as monodentate ligand:: Halogen bonding driven formation of discrete 2:1 aggregates with 1,2,4,5-tetrafluoro-3,6-diiodobenzene
    Liantonio, R
    Logothetis, TA
    Messina, MT
    Metrangolo, P
    De Santis, A
    Pilati, T
    Resnati, G
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 2002, 67 (09) : 1373 - 1382
  • [24] A polymeric sodium complex of 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine
    Constable, EC
    Housecroft, CE
    Kariuki, BM
    Kelly, N
    Smith, CB
    CHEMICAL COMMUNICATIONS, 2001, (20) : 2134 - 2135
  • [25] Reactions of first-row metal(II) triflates with 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine
    Manikoff, Jillian
    Cranswick, Matthew
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 252
  • [26] Pericyclic domino reactions with 3,6-bis(trifluoromethyl)-1,2,4,5-tetrazine: A convenient entry into azo cage compounds
    Klindert, T
    vonHagel, P
    Baumann, L
    Seitz, G
    JOURNAL FUR PRAKTISCHE CHEMIE-CHEMIKER-ZEITUNG, 1997, 339 (07): : 623 - 632
  • [27] The crystal structure of 1,8-bis(pyridin-4-ylethynyl)anthracene-1,2,4,5-tetrafluoro-3,6-diiodobenzene (2/1), C62H32F4I2N4
    Zhang, Lingfan
    Ding, Man-Hua
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2020, 235 (04): : 919 - 921
  • [28] A near planar disilver complex of 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine
    Constable, EC
    Housecroft, CE
    Kariuki, BM
    Kelly, N
    Smith, CB
    INORGANIC CHEMISTRY COMMUNICATIONS, 2002, 5 (03) : 199 - 202
  • [29] Crystal structure of 3,6-bis(2-chlorophenyl)-1,2,4,5-tetrazine: the acaricide clofentezine
    Kang, Gihaeng
    Cho, Seonghwa
    Lee, Sangjin
    Kim, Tae Ho
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : O1135 - +
  • [30] Study on the Azido-Tetrazolo Tautomerizations of 3,6-Bis(azido)-1,2,4,5-tetrazine
    Zhao, Dan
    Lv, Meifang
    Cai, Chun
    PROPELLANTS EXPLOSIVES PYROTECHNICS, 2015, 40 (05) : 627 - 631