Cis- and trans-influences in [PtCl2(SPh2)2]

被引:9
|
作者
Johansson, MH [1 ]
Oskarsson, Å [1 ]
Lövqvist, K [1 ]
Kiriakidou, F [1 ]
Kapoor, P [1 ]
机构
[1] Lund Univ, S-22100 Lund, Sweden
关键词
D O I
10.1107/S010827010100960X
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Both cis- and trans-dichlorobis(diphenyl sulfide)platinum(II), [PtCl2(C12H10S)(2)], crystallize as mononuclear pseudo-square-planar complexes. In the cis compound, the Pt-Cl distances are 2.295 (2) and 2.319 (2) Angstrom, and the Pt-S distances are 2.280 (2) and 2.283 (2) Angstrom. In the trans compound, Pt is located on a centre of inversion and the Pt-Cl and Pt-S distances are 2.2786 (15) and 2.3002 (12) Angstrom, respectively.
引用
收藏
页码:1053 / 1055
页数:3
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