1,1-Bis(dimethylamino)-2,2-difluoroethene, a diverse building block for the preparation of difluoroalkyl molecules. Acylation and condensation reactions

被引：4
|
作者：
Xu, Yuelian [1 ]
Lopez, Simon E. [1 ]
Dolbier, William R., Jr. [1 ]
机构：
[1] Univ Florida, Dept Chem, POB 117200, Gainesville, FL 32611 USA
来源：
JOURNAL OF FLUORINE CHEMISTRY | 2020年 / 229卷
基金：
美国国家科学基金会;
关键词：
Fluorinated ketene aminal; Acylation reactions; FLUORINE;
D O I：
10.1016/j.jfluchem.2019.109432
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
1,1-Bis(dimethylamino)-2,2-difluoroethene has been shown to be a diverse and highly effective building block for the preparation of a variety of fluorinated compounds. Reported here are preliminary results of its use for acylation reactions with acyl chlorides to form 2,2-difluoroketoacetamides as well as for its direct condensation with various acidic a-hydrogen carbon compounds to form a variety of functionalized difluoromethyl enamines.
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页数：5
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