Synthesis, structure, and application of [PhNMe2H][B{C6F4C(C6F5)2F}4]

被引：20

作者：

Rodriguez, G ^{[1
]}

Brant, P ^{[1
]}

机构：

[1] ExxonMobil, Baytown Polymers Ctr, Baytown, TX 77521 USA

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 11期

关键词：

D O I：

10.1021/om001080i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new perfluorinated tetraaryl borate [B{C6F4C(C6F5)(2)F}(4)](-) (3) has been prepared and characterized. The X-ray structural analysis of [C6H5N(H)-(CH3)(2)][3] confirms the tetrahedral geometry about the boron. The performance of 3 as a weakly coordinating anion in ethylene polymerization was evaluated and compared with that of B(C6F5)(4)(-) and B(3,5-(CF3)(2)C6H3)(4)(-). The stability of 3 throughout polymerization was evaluated by analyzing anion residues in a polymer sample using mass spectroscopy.

引用

页码：2417 / 2420

页数：4

共 50 条

[21] SYNTHESIS AND REACTIVITY OF TRINUCLEAR GOLD(III) DITHIOLATE COMPLEXES - X-RAY STRUCTURE OF [AU(C6F5)(S2C6H4)](3) AND [AU(C6F5)(S2C6H4)(SC(6)H(4)SPPH(3))]
CERRADA, E
FERNANDEZ, EJ
JONES, PG
LAGUNA, A
LAGUNA, M
TERROBA, R
[J]. ORGANOMETALLICS, 1995, 14 (12) : 5537 - 5543
[22] ASIS EFFECTS ON H-1 AND F-19 NUCLEI OF DIPOLAR SOLUTES IN C6F6, C6H5F, PARA C6H4F2, 1,2,4,5-C6H2F4 AND C6H6
MOSBO, J
VERKADE, JG
[J]. JOURNAL OF MAGNETIC RESONANCE, 1972, 8 (03) : 250 - &
[23] B(C6F5)3- and HB(C6F5)2-mediated transformations of isothiocyanates
Fischer, Malte
Schmidtmann, Marc
[J]. CHEMICAL COMMUNICATIONS, 2020, 56 (46) : 6205 - 6208
[24] STEREOSPECIFIC POLYMERIZATION OF METHYL-METHACRYLATE INITIATED BY DIMETHYLZIRCONOCENE/B(C6F5)(3) (OR PH(3)CB(C6F5)(4))/ZN(C2H5)(2)
SOGA, K
DENG, H
YANO, T
SHIONO, T
[J]. MACROMOLECULES, 1994, 27 (26) : 7938 - 7940
[25] Synthesis and structure of [Tl(C6F5)(2)Cl{Au(C6F5)(3)(PPh(2)CH(2)PPh(2)(O))}(2)]
Alvarez, B
Fernandez, EJ
Gimeno, MC
Jones, PG
Laguna, A
Laguna, M
LopezdeLuzuriaga, JM
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 525 (1-2) : 109 - 113
[26] SYNTHESIS, X-RAY STRUCTURE, AND REACTIVITY OF (NBU4)2[PT2(MU-C6F5)2(C6F5)4].H2O AND (NBU4)[PT2AG(MU-C6F5)2(C6F5)4O(C2H5)2] - THE 1ST COMPLEXES CONTAINING BRIDGING PENTAFLUOROPHENYL GROUPS
USON, R
FORNIES, J
TOMAS, M
CASAS, JM
COTTON, FA
FALVELLO, LR
LLUSAR, R
[J]. ORGANOMETALLICS, 1988, 7 (11) : 2279 - 2285
[27] Oxidation of [M(η-C5H5)2], M = Cr, Fe or Co, by the new Bronsted acid H2O•B(C6F5)3 yielding the salts [M(η-C5H5)2]+A-, where A- = [(C6F5)3B(μ-OH)B(C6F5)3]- or [(C6F5)3BOH•••H2OB(C6F5)3]-
Doerrer, LH
Green, MLH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (24): : 4325 - 4329
[28] Zinc(II) η1- and η2-toluene complexes:: Structure and bonding in Zn(C6F5)2•(toluene) and Zn(C6F4-2-C6F5)2•(toluene)
Guerrero, Antonio
Martin, Eddy
Hughes, David L.
Kaltsoyannis, Nikolas
Bochmann, Manfred
[J]. ORGANOMETALLICS, 2006, 25 (14) : 3311 - 3313
[29] Synthesis and molecular structure of Pd2(C6F5)2[μ-P(C6F5)CH2CH2P(C6F5)2]2.: A rare example of P-C bond cleavage in a fluoroaryl phosphine
Heyn, RH
Görbitz, CH
[J]. ORGANOMETALLICS, 2002, 21 (13) : 2781 - 2784
[30] Reaction of AlR3 with [CPh3][B(C6F5)4]:: Facile degradation of [B(C6F5)4]- by transient "[AlR2]+"
Bochmann, M
Sarsfield, MJ
[J]. ORGANOMETALLICS, 1998, 17 (26) : 5908 - 5912

← 1 2 3 4 5 →