Reaction of a bulky phosphite with [Ru3(CO)12]:: The molecular structure of one of the decomposition products

被引：5

作者：

Magwaza, Abraham O. ^{[2
]}

Meijboom, Reinout ^{[1
]}

Muller, Alfred ^{[1
]}

Mavunkal, Ipe J. ^{[2
]}

机构：

[1] Univ Orange Free State, Dept Chem, ZA-9300 Bloemfontein, South Africa

[2] Univ Botswana, Dept Chem, Gaborone, Botswana

来源：

INORGANICA CHIMICA ACTA | 2008年 / 361卷 / 01期

基金：

新加坡国家研究基金会;

关键词：

ruthenium; phosphite; cluster; crystal structure;

D O I：

10.1016/j.ica.2007.08.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mono- and bis-substituted phosphite complexes [Ru-3(CO)(12-x) L-x] (L = tris(2,4-di-tert-butylphenyl) phosphite; x = 1, 2) were synthesized by simple substitution reactions, and were characterized by spectroscopic methods. The monosubstituted ruthenium complex dis-proportionates in acetone producing a mononuclear ruthenium complex as one of the decomposition products. Single crystal X-ray diffraction analysis established the molecular structure of this new compound. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：335 / 340

页数：6

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