Reaction of a bulky phosphite with [Ru3(CO)12]:: The molecular structure of one of the decomposition products

被引：5
|
作者：
Magwaza, Abraham O. [2 ]
Meijboom, Reinout [1 ]
Muller, Alfred [1 ]
Mavunkal, Ipe J. [2 ]
机构：
[1] Univ Orange Free State, Dept Chem, ZA-9300 Bloemfontein, South Africa
[2] Univ Botswana, Dept Chem, Gaborone, Botswana
来源：
INORGANICA CHIMICA ACTA | 2008年 / 361卷 / 01期
基金：
新加坡国家研究基金会;
关键词：
ruthenium; phosphite; cluster; crystal structure;
D O I：
10.1016/j.ica.2007.08.008
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Mono- and bis-substituted phosphite complexes [Ru-3(CO)(12-x) L-x] (L = tris(2,4-di-tert-butylphenyl) phosphite; x = 1, 2) were synthesized by simple substitution reactions, and were characterized by spectroscopic methods. The monosubstituted ruthenium complex dis-proportionates in acetone producing a mononuclear ruthenium complex as one of the decomposition products. Single crystal X-ray diffraction analysis established the molecular structure of this new compound. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：335 / 340
页数：6
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