Defect engineering of two-dimensional transition metal dichalcogenides

被引:356
|
作者
Lin, Zhong [1 ,2 ]
Carvalho, Bruno R. [1 ,2 ,3 ]
Kahn, Ethan [2 ,4 ]
Lv, Ruitao [5 ]
Rao, Rahul [6 ,7 ]
Terrones, Humberto [8 ]
Pimenta, Marcos A. [3 ]
Terrones, Mauricio [1 ,2 ,4 ,9 ,10 ]
机构
[1] Penn State Univ, Dept Phys, 104 Davey Lab, University Pk, PA 16802 USA
[2] Penn State Univ, Ctr Dimens & Layered Mat 2, University Pk, PA 16802 USA
[3] Univ Fed Minas Gerais, Dept Fis, BR-30123970 Belo Horizonte, MG, Brazil
[4] Penn State Univ, Dept Mat Sci & Engn, University Pk, PA 16802 USA
[5] Tsinghua Univ, Sch Mat Sci & Engn, Key Lab Adv Mat MOE, Beijing 100084, Peoples R China
[6] Air Force Res Lab, Mat & Mfg Directorate, RXAS, Wright Patterson AFB, OH 45433 USA
[7] UES Inc, Dayton, OH 45432 USA
[8] Rensselaer Polytech Inst, Dept Phys Appl Phys & Astron, 110 Eighth St, Troy, NY 12180 USA
[9] Penn State Univ, Dept Chem, University Pk, PA 16802 USA
[10] Shinshu Univ, Inst Carbon Sci & Technol, 4-17-1 Wakasato, Nagano 3808553, Japan
来源
2D MATERIALS | 2016年 / 3卷 / 02期
基金
中国国家自然科学基金; 美国国家科学基金会;
关键词
two-dimensional material; transition metal dichalcogenides; molybdenum disulfide; defects; electronic properties; SINGLE-LAYER MOS2; DER-WAALS HETEROSTRUCTURES; ACTIVE EDGE SITES; HYDROGEN EVOLUTION; RAMAN-SPECTROSCOPY; GRAIN-BOUNDARIES; MONOLAYER MOS2; ULTRATHIN NANOSHEETS; VAPOR-DEPOSITION; PHOTOLUMINESCENCE;
D O I
10.1088/2053-1583/3/2/022002
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Two-dimensional transition metal dichalcogenides (TMDs), an emerging family of layered materials, have provided researchers a fertile ground for harvesting fundamental science and emergent applications. TMDs can contain a number of different structural defects in their crystal lattices which significantly alter their physico-chemical properties. Having structural defects can be either detrimental or beneficial, depending on the targeted application. Therefore, a comprehensive understanding of structural defects is required. Here we review different defects in semiconducting TMDs by summarizing: (i) the dimensionalities and atomic structures of defects; (ii) the pathways to generating structural defects during and after synthesis and, (iii) the effects of having defects on the physico-chemical properties and applications of TMDs. Thus far, significant progress has been made, although we are probably still witnessing the tip of the iceberg. A better understanding and control of defects is important in order to move forward the field of Defect Engineering in TMDs. Finally, we also provide our perspective on the challenges and opportunities in this emerging field.
引用
收藏
页数:21
相关论文
共 50 条
  • [22] Two-Dimensional Transition Metal Dichalcogenides under Electron Irradiation: Defect Production and Doping
    Komsa, Hannu-Pekka
    Kotakoski, Jani
    Kurasch, Simon
    Lehtinen, Ossi
    Kaiser, Ute
    Krasheninnikov, Arkady V.
    PHYSICAL REVIEW LETTERS, 2012, 109 (03)
  • [23] Excitonic Complexes in Two-Dimensional Transition Metal Dichalcogenides
    Chen, Xiaotong
    Lian, Zhen
    Meng, Yuze
    Ma, Lei
    Shi, Su-Fei
    NATURE COMMUNICATIONS, 2023, 14 (01)
  • [24] Nonlinear optics of two-dimensional transition metal dichalcogenides
    Wen, Xinglin
    Gong, Zibo
    Li, Dehui
    INFOMAT, 2019, 1 (03) : 317 - 337
  • [25] Chemically tailoring two-dimensional transition metal dichalcogenides
    Chen, Xin
    McDonald, Aidan
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
  • [26] Laser printed two-dimensional transition metal dichalcogenides
    Abbas, Omar Adnan
    Lewis, Adam Henry
    Aspiotis, Nikolaos
    Huang, Chung-Che
    Zeimpekis, Ioannis
    Hewak, Daniel W.
    Sazio, Pier
    Mailis, Sakellaris
    SCIENTIFIC REPORTS, 2021, 11 (01)
  • [27] Laser printed two-dimensional transition metal dichalcogenides
    Omar Adnan Abbas
    Adam Henry Lewis
    Nikolaos Aspiotis
    Chung-Che Huang
    Ioannis Zeimpekis
    Daniel W. Hewak
    Pier Sazio
    Sakellaris Mailis
    Scientific Reports, 11
  • [28] Introduction: Two-Dimensional Layered Transition Metal Dichalcogenides
    Duan, Xiangfeng
    Zhang, Hua
    CHEMICAL REVIEWS, 2024, 124 (19) : 10619 - 10622
  • [29] Strain regulation of two-dimensional transition metal dichalcogenides
    Zhou, Lu
    Fu, Lei
    CHINESE SCIENCE BULLETIN-CHINESE, 2019, 64 (17): : 1817 - 1831
  • [30] Strong correlations in two-dimensional transition metal dichalcogenides
    Wei Ruan
    Yuanbo Zhang
    Science China Physics, Mechanics & Astronomy, 2023, 66