Microstructure Characterization of Polyolefins. TREF and CRYSTAF

被引：0
|
作者：
Monrabal, Benjamin [1 ]
机构：
[1] Polymer Char, E-46980 Paterna, Spain
来源：
PROGRESS IN OLEFIN POLYMERIZATION CATALYSTS AND POLYOLEFIN MATERIALS, PROCEEDINGS OF THE FIRST ASIAN POLYOLEFIN WORKSHOP | 2006年 / 161卷
关键词：
D O I：
暂无
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The introduction of single site catalysts in the polyolefins industry has opened new possibilities in polymer design through multiple reactor-catalyst systems. Very often this approach results in bimodal or trimodal composition distributions and unique composition-molar mass dependence; the performance of these resins is very sensitive to small microstructure variations. The analysis of the Chemical Composition Distribution has been, in those cases, the most important analytical task. The separation techniques being used in the characterization of the Chemical Composition Distribution, TREF and CRYSTAF, are discussed with examples for various types of polyolefins.
引用
收藏
页码：35 / 42
页数：8
相关论文
共 50 条
  • [41] Development of an automated cross-fractionation apparatus (TREF-GPC) for a full characterization, of the bivariate distribution of polyolefins
    Ortin, Alberto
    Monrabal, Benjamin
    Sancho-Tello, Juan
    MACROMOLECULAR SYMPOSIA, 2007, 257 : 13 - 28
  • [42] Dielectric and fluorescent probes to investigate glass transition, melt and crystallization in polyolefins.
    van den Berg, O
    Jager, WF
    Sengers, WGF
    Wübbenhorst, M
    Picken, SJ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U544 - U544
  • [43] Hyperbranched poly(siloxysilane)s:: Control of growth and end functionalization with polyolefins.
    Gong, CG
    Miravet, JF
    Fréchet, JMJ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 217 : U448 - U448
  • [44] Stratification of processes near surfaces in multi-phase polyolefins.
    Urban, MW
    Stegge, JM
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 222 : U243 - U243
  • [45] Overview of synthesis and basic chemical structure/physical property relationships in polyolefins.
    McGrath, JE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 220 : U297 - U297
  • [46] Analysing the chemical composition distribution of ethylene-acrylate copolymers:: Comparison of HT-HPLC, CRYSTAF and TREF
    Albrecht, Andreas
    Bruell, Robert
    Macko, Tibor
    Sinha, Pritish
    Pasch, Harald
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2008, 209 (18) : 1909 - 1919
  • [47] GRAFTING OF BLOCK COPOLYMERS HAVING PENDANT PEROXIDE GROUPS ONTO POLYOLEFINS.
    Suzuki, Nobuyoshi
    Aoshima, Kazuyoshi
    Yamamoto, Takashi
    Moriya, Yasuo
    Kobunshi Ronbunshu, 1987, 44 (02): : 89 - 95
  • [48] Synthesis of well-defined long chain-branched polyolefins.
    Wiyatno, W
    Fox, PA
    Waymouth, RM
    Fuller, GG
    Hawker, CJ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 219 : U366 - U366
  • [49] ADHESION AND PROPERTY ENHANCEMENT VIA ACRYLIC-ACID GRAFTED POLYOLEFINS.
    Ludwig, Peter J.
    Modern Plastics, 1983, 60 (01): : 81 - 82
  • [50] Development of an Integrated On-Line 2D Analytical TREF-High Throughput SEC Technique for Polyolefins Characterization
    Yu, Youlu
    Hildebrand, Melvin
    MACROMOLECULAR SYMPOSIA, 2020, 390 (01)
12345