Overcharge protection of lithium-ion batteries above 4 V with a perfluorinated phenothiazine derivative

被引：25

作者：

Kaur, Aman Preet ^{[1
]}

Casselman, Matthew D. ^{[1
]}

Elliott, Corrine F. ^{[1
]}

Parkin, Sean R. ^{[1
]}

Risko, Chad ^{[1
,2
]}

Odom, Susan A. ^{[1
]}

机构：

[1] Univ Kentucky, Dept Chem, Lexington, KY 40506 USA

[2] Univ Kentucky, Ctr Appl Energy Res, 3572 Iron Works Pike, Lexington, KY 40511 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2016年 / 4卷 / 15期

基金：

美国国家科学基金会;

关键词：

REDOX SHUTTLE ADDITIVES; OVERDISCHARGE PROTECTION; CHEMICAL OVERCHARGE; PERFORMANCE; MECHANISMS; CATHOLYTE;

D O I：

10.1039/c5ta10375d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electron-withdrawing substituents are introduced onto the phenothiazine core to raise its oxidation potential for use as a redox shuttle in high-voltage lithium-ion batteries. A perfluorinated derivative oxidizes at 4.3 V vs. Li+/0, and functions for ca. 500 h of 100% overcharge in LiNi0.8Co0.15Al0.05O2/graphite coin cells at a charging rate of C/10.

引用

页码：5410 / 5414

页数：5

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