Tetrakis[μ-2-(3,4-dimethoxyphenyl)acetato]- κ4O:O′;κ3O,O′:O;κ3O:O,O′bis{[2-(3,4-dimethoxyphenyl)acetato- κ2O,O′](1,10-phenanthroline-κ2N,N′)samarium(III)}

被引：0
|
作者：
Liu, Jia-Lu
Li, Hua-Qiong
Zhao, Guo-Liang [1 ]
机构：
[1] Zhejiang Normal Univ, Coll Chem & Life Sci, Jinhua 321004, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
D O I：
10.1107/S1600536810037153
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the centrosymmetric dinuclear title complex, [Sm-2-( C10H11O4)(6)(C12H8N2)(2)], the Sm-III ion is nine-coordinated by seven O atoms of five 2-(3,4-dimethoxyphenyl)acetate (DMPA) ligands and two N atoms of one bis- chelating 1,10phenanthroline (phen) ligand, forming a distorted tricapped trigonal- prismatic environment. The DMPA ligands coordinate in bis- chelate, bridging and bridging tridentate modes. An intramolecular C-H center dot center dot center dot O hydrogen bond occurs. Intermolecular C-H center dot center dot center dot O interactions are also present in the crystal.
引用
收藏
页码：M1377 / U398
页数：17
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