Kinetics investigation on the hydrogenation of acrylonitrile-butadiene rubber latex by using new catalytic reaction system

被引：9
|
作者：
Ou, Haoming [1 ]
Wang, Yang [1 ]
Zhou, Wei [1 ]
Peng, Xiaohong [1 ]
机构：
[1] South China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510640, Guangdong, Peoples R China
来源：
CATALYSIS COMMUNICATIONS | 2016年 / 84卷
基金：
中国国家自然科学基金;
关键词：
Hydrogenation; Acrylonitrile-butadiene rubber latex; Kinetics; NBR LATEX; SELENIUM; DIIMIDE; HYDRAZINE;
D O I：
10.1016/j.catcom.2016.03.006
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The kinetics of hydrogenation of acrylonitrile-butadiene rubber latex with hydrazine hydrate/hydrogen peroxide/selenium catalytic reaction system was investigated by calculating the initial reaction rate constants. The reaction rate constants of the reaction system were obtained by initial reaction measurements of different reactant dosages, such as selenium, hydrazine hydrate, and hydrogen peroxide. Hydrogenation rate constants and reaction order corresponding to the various factors were obtained from the hydrogenation kinetic data. The kinetic equation of this reaction system between 50-70 degrees C and the reaction activation energy was derived. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：183 / 187
页数：5
相关论文
共 50 条
  • [31] Amelioration of acrylonitrile-butadiene copolymer properties using natural rubber graft p-aminophenol
    El-Wakil, A. A.
    JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 104 (01) : 27 - 34
  • [32] A new liquid rubber-assisted dispersion of organoclay in carbon black filled carboxylated acrylonitrile-butadiene rubber matrix
    Naval Materials Research Laboratory, Shil-Badlapur Road, Anandnagar, Mumbai 421506, Maharashtra, India
    不详
    Sreenivasan, P. (praveens76@gmail.com), 1600, John Wiley and Sons Inc (128):
  • [33] Water sorption kinetics of acrylonitrile-butadiene rubber/poly(ethylene-co-vinyl acetate)/organoclay nanocomposites
    Razavi-Nouri, Mohammad
    Karami, Mahmoud
    POLYMER, 2018, 154 : 101 - 110
  • [34] Electron-beam-induced crosslinking of natural rubber/acrylonitrile-Butadiene rubber latex blends in the presence of ethoxylated pentaerythritol tetraacrylate used as a crosslinking promoter
    Chowdhury, Rajesh
    JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 103 (02) : 1206 - 1214
  • [35] Study on the non-liquid-phase coordination crosslinking reaction of acrylonitrile-butadiene rubber/copper sulfate composites
    Mou Haiyan
    Shen Fei
    Cao Yuanyi
    Yuan Xiaofang
    Wu Chifei
    ACTA POLYMERICA SINICA, 2008, (09) : 910 - 914
  • [36] Enhancements in damping properties and thermal conductivity of acrylonitrile-butadiene rubber by using hindered phenol modified alumina
    Dong, Huanhuan
    Jiang, Yang
    Zhang, Yong
    JOURNAL OF APPLIED POLYMER SCIENCE, 2022, 139 (30)
  • [37] Effects of fiber content and resorcinol-formaldehyde-latex treatment on composite properties of acrylonitrile-butadiene rubber reinforced with chopped aramid fibers
    Li, Zhuo
    Li, Yingzhe
    Wan, Sheng
    Cheng, Junmei
    Li, Lin
    Yue, Cong
    POLYMER COMPOSITES, 2020, 41 (07) : 2713 - 2723
  • [38] Development of thermoplastic vulcanizates based on in situ synthesized thermoplastic polyurethane and acrylonitrile-butadiene rubber: the influence of the curing system
    Andrea Kohári
    Tamás Bárány
    Journal of Polymer Research, 2022, 29
  • [39] Development of thermoplastic vulcanizates based on in situ synthesized thermoplastic polyurethane and acrylonitrile-butadiene rubber: the influence of the curing system
    Kohari, Andrea
    Barany, Tamas
    JOURNAL OF POLYMER RESEARCH, 2022, 29 (09)
  • [40] Selective hydrogenation of nitrile butadiene rubber latex using Catmetium®RF 4 catalyst
    Tong, Weichao
    Chen, Hanchu
    Zhang, Yuxiang
    Zhang, Zhuo
    Fu, Yunlei
    Qi, Haocheng
    Zhou, Defang
    Li, Yanyan
    Wang, Hui
    CATALYSIS TODAY, 2023, 407 : 80 - 88
12345