Decomposition mechanism of Birch alkylation products of α-tetralones

被引：3
|
作者：
Labadie, GR
Estiú, GL
Cravero, RM
Sierra, MG
机构：
[1] Univ Nacl Rosario, Fac Ciencias Bioquim & Farmaceut, Dept Quim Organ, IQUIOS, RA-2000 Rosario, Argentina
[2] Natl Univ La Plata, Fac Ciencias Exactas, Dept Quim, CEQUINOR, RA-1900 La Plata, Argentina
[3] Univ Buenos Aires, Dept Quim Inorgan Analitica & Quim Fis, Buenos Aires, DF, Argentina
来源：
JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM | 2003年 / 635卷
关键词：
1,4 dienones radicals; decomposition pathways; beta-elimination; oxygen addition;
D O I：
10.1016/S0166-1280(03)00407-X
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The Birch alkylation reaction, used in several synthetic paths in organic chemistry, faces the complication of the lack of stability of its products. Different mechanisms have been suggested for the decomposition step, which render different decomposition products. The comparison of these mechanisms can help to understand the origin of this complication, and, at the same time, to overcame it. This study shows the results of theoretical calculations applied to their comparison. The conclusions are in agreement with our previous experimental results. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码：173 / 182
页数：10
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