A zeolite supramolecular framework with LTA topology based on a tetrahedral metal-organic cage

被引:24
|
作者
Zhang, Hai-Xia [1 ]
Yan, Xiaodong [1 ]
Chen, Yu-Xin [1 ]
Zhang, Shu-Heng [1 ]
Li, Tao [1 ]
Han, Wang-Kang [1 ]
Bao, Ling-Yu [1 ]
Shen, Rui [1 ]
Gu, Zhi-Guo [1 ,2 ]
机构
[1] Jiangnan Univ, Sch Chem & Mat Engn, Minist Educ, Key Lab Synthet & Biol Colloids, Wuxi 214122, Peoples R China
[2] Jiangnan Univ, Sch Chem & Mat Engn, Int Joint Res Ctr Photorespons Mol & Mat, Wuxi 214122, Peoples R China
基金
中国国家自然科学基金;
关键词
SPIN-CROSSOVER; MOLECULAR CAGES; IODINE; ADSORPTION; POLYHEDRA; SORPTION; DESIGN;
D O I
10.1039/c8cc08965e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An unprecedented zeolite supramolecular framework featuring truncated cuboctahedral and truncated octahedral cavities was self-assembled from tetrahedral metal-organic cationic cages and tetrahedral anions. This crystalline porous material could trap iodine and organic dye molecules, and its solid state spin-crossover behavior was affected by guest encapsulation.
引用
收藏
页码:1120 / 1123
页数:4
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