Transition Metal-Catalyzed C-H Oxidation of Saturated Hydrocarbons with Molecular Oxygen

被引：9

作者：

Komiya, Naruyoshi ^{[1
,2
]}

Murahashi, Shun-Ichi ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Toyonaka, Osaka 5608531, Japan

[2] Jikei Univ, Sch Med, Chem Lab, Chofu, Tokyo 1828570, Japan

来源：

CHEMICAL RECORD | 2021年 / 21卷 / 08期

基金：

日本学术振兴会;

关键词：

C-H oxidation; Saturated hydrocarbons; Molecular oxygen; Transition metal catalysts; CYTOCHROME-P-450 TYPE OXIDATION; BAEYER-VILLIGER OXIDATION; AEROBIC OXIDATION; ACYL CYANIDES; ENANTIOSELECTIVE OXIDATION; NICKEL(II) COMPLEXES; PERACETIC-ACID; SILYL ETHERS; RUTHENIUM; ALKANES;

D O I：

10.1002/tcr.202100154

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The C-H oxidation of saturated hydrocarbons to the corresponding alcohols and ketones can be performed efficiently at room temperature with molecular oxygen (1 atm) in the presence of acetaldehyde and catalysts such as Fe, Cu(OH)(2), and CuCl2-18-crown-6 complex. Moreover, extremely high turnover numbers (>27,000) have been obtained for the C-H oxidation of saturated hydrocarbons with molecular oxygen (1 atm) using a combination of Cu(OAc)(2) and acetonitrile at 70 degrees C. Related oxidation reactions such as epoxidation, Baeyer-Villiger reaction, acetoxylation of beta-lactams with molecular oxygen and a suitable aldehyde at room temperature are described.

引用

页码：1928 / 1940

页数：13

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