Silver Complexes [Ph3PCH2CH2PPh3]2+[Ag2Cl4]2-, [Ph3PCH2OCH3]2+[Ag2Cl4]2-, [Ph3P(i-Am)]2+[Ag2Br4]2-, [Ph3PC6H11-cyclo]2+[Ag2Br4]2-, [Ph3PCH2Ph]2+[Ag2Br4]2-, and [Ph3PCH=CH2]n+[Ag2Br3]n-,7 [Me4P]n+[Ag2Br3]n-: Synthesis and Structure

被引：2

作者：

Sharutin, V. V. ^{[1
]}

Sharutina, O. K. ^{[1
]}

Senchurin, V. S. ^{[1
]}

Neudachina, A. N. ^{[1
]}

机构：

[1] Natl South Ural State Res Univ, Pr Lenina 76, Chelyabinsk 454080, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2016年 / 61卷 / 04期

关键词：

802.2 Chemical Reactions - 804 Chemical Products Generally;

D O I：

10.1134/S0036023616040173

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Silver complexes [Ph3PCH2CH2PPh3](2+)[Ag2Cl4](2-) (I), [Ph3PCH2OCH3](2)(+)[Ag2Cl4](2-) (II), [Ph3P(i-Am)](2)(+)[Ag2Br4](2-) (III), [Ph3PC6H11-cyclo](2)(+)[Ag2Br4](2-) (IV), [Ph3PCH2Ph](2)(+)[Ag2Br4](2-) (V), [Ph3PCH = CH2](n)(+)[Ag2Br3](n)(n-) (VI), and [Me4P](n)(+)[Ag2Br3](n)(n-) (VII) have been synthesized by the reaction between tetraorganylphosphonium halides and silver chloride or silver bromide in dimethylsulfoxide. According to X-ray diffraction data, the ionic complexes are built of tetraorganylphosphonium cations and binuclear (I-V) or polynuclear (VI, VII) anions. In the anions of complexes VI and VII, silver atoms are tetracoordinated, and bromine atoms have coordination numbers of 2 and 4.

引用

页码：451 / 460

页数：10

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