catena-Poly[[aqua(4,4′-bipyridine-κ2N,N′)manganese(II)]-μ-3-(4-carboxylatophenoxy)propionato-κ3O:O′,O"]

被引：3
|
作者：
Kong, Li-Li
Gao, Shan
Huo, Li-Hua
Ng, Seik Weng [1 ]
机构：
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[2] Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词：
D O I：
10.1107/S160053680705218X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the crystal structure of the polymeric title compound, [Mn(C10H8N2)(C10H8O5)(H2O)](n), the Mn-II atom is O,O '-chelated by the aromatic carboxylate end of the 3-(4-carboxylatophenoxy) propionate dianion and is covalently bonded ( through one O atom) by the aliphatic carboxylate end of another dianion; it is also coordinated by a water molecule. The compound adopts a helical chain structure that propagates along the c axis of the orthorhombic unit cell. The coordinated water molecule engages in both intrachain and interchain hydrogen bonding; the interchain hydrogen bonds result in a honeycomb motif. The compound crystallizes as a 0.36:0.64 inversion twin.
引用
收藏
页码：M2851 / U2030
页数：11
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