Effect of the sulfide group on photopolymerization kinetics of di(meth)acrylates

被引：13
|
作者：
Andrzejewska, E [1 ]
机构：
[1] KAROLINSKA INST,DEPT DENT MAT & TECHNOL,S-14104 HUDDINGE,STOCKHOLM,SWEDEN
来源：
POLYMER BULLETIN | 1996年 / 37卷 / 02期
关键词：
D O I：
10.1007/BF00294122
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The photopolymerization of four analogous monomers: 2,2'-thiobisethanol diacrylate and its dimethacrylate plus 2,2'-oxybisethanol diacrylate and its dimethacrylate has been studied by isothermal differential scanning calorimetry (DSC) over a range of incident light intensities. The results obtained prove that the sulfide group accelerates polymerization both in the presence and absence of oxygen and enhances the conversion. The light intensity exponents for each monomer were determined and the mechanism of termination was discussed. The intensity exponents of sulfur-containing monomers are lower than their corresponding oxygen analogues, pointing to a greater participation of the bimolecular termination during their polymerization.
引用
收藏
页码：199 / 206
页数：8
相关论文
共 50 条
  • [31] Self-initiation of UV photopolymerization reactions using tetrahalogenated bisphenol A (meth)acrylates
    Théophile Pelras
    Wolfgang Knolle
    Sergej Naumov
    Katja Heymann
    Olesya Daikos
    Tom Scherzer
    Photochemical & Photobiological Sciences, 2017, 16 : 649 - 662
  • [32] Kinetics of photopolymerization of acrylates studied with a cure monitor and photoDSC
    Khudyakov, IV
    Legg, JC
    Purvis, MB
    Overton, BJ
    OPTICAL FIBER RELIABILITY AND TESTING, 1999, 3848 : 151 - 156
  • [33] Kinetics of photopolymerization of acrylates with functionality of 1-6
    Khudyakov, IV
    Legg, JC
    Purvis, MB
    Overton, BJ
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1999, 38 (09) : 3353 - 3359
  • [34] Photopolymerization kinetics of tributylmethylammonium-based (meth)acrylate ionic liquids and the effect of water
    Zhou, Hui
    Jimenez, Zulma
    Pojman, John A.
    Paley, Mark S.
    Hoyle, Charles E.
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (11) : 3766 - 3773
  • [35] Kinetics of photopolymerization of acrylates with functionality of 1-6
    Khudyakov, Igor V.
    Legg, Jodi C.
    Purvis, Michael B.
    Overton, Bob J.
    Industrial and Engineering Chemistry Research, 1999, 38 (09): : 3353 - 3359
  • [36] Kinetics of radical polymerization of (meth)acrylates with a perfluorinated side chain
    Guyot, B
    Améduri, B
    Boutevin, B
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 1999, 200 (09) : 2111 - 2121
  • [37] Kinetics of photopolymerization of neat acrylates and acrylate coatings.
    Khudyakov, IV
    Purvis, MB
    Turro, NJ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 222 : U321 - U321
  • [38] KINETICS AND MECHANISM OF FORMATION OF POLYMER EMULSIONS ON THE BASE OF (METH) ACRYLATES
    GOLDFEIN, MD
    KOZHEVNIKOV, NV
    TRUBNIKOV, AV
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1991, 33 (10): : 2035 - 2049
  • [39] Polymerization kinetics of (meth)acrylates in self-assembled structures
    University of Colorado, Boulder, CO 80309-0424, United States
    Am Chem Soc Polym Prepr Div Polym Chem, 2 (508-509):
  • [40] Kinetics and mechanism of formation of polymer emulsions on the base of (meth)acrylates
    Gol'dfejn, M.D.
    Kozhevnikov, N.V.
    Trubnikov, A.V.
    Vysokomolekularnye Soedineniya. Seriya A, 1991, 33 (10): : 2035 - 2049
12345