Effect of the sulfide group on photopolymerization kinetics of di(meth)acrylates

被引：13
|
作者：
Andrzejewska, E [1 ]
机构：
[1] KAROLINSKA INST,DEPT DENT MAT & TECHNOL,S-14104 HUDDINGE,STOCKHOLM,SWEDEN
来源：
POLYMER BULLETIN | 1996年 / 37卷 / 02期
关键词：
D O I：
10.1007/BF00294122
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The photopolymerization of four analogous monomers: 2,2'-thiobisethanol diacrylate and its dimethacrylate plus 2,2'-oxybisethanol diacrylate and its dimethacrylate has been studied by isothermal differential scanning calorimetry (DSC) over a range of incident light intensities. The results obtained prove that the sulfide group accelerates polymerization both in the presence and absence of oxygen and enhances the conversion. The light intensity exponents for each monomer were determined and the mechanism of termination was discussed. The intensity exponents of sulfur-containing monomers are lower than their corresponding oxygen analogues, pointing to a greater participation of the bimolecular termination during their polymerization.
引用
收藏
页码：199 / 206
页数：8
相关论文
共 50 条
  • [1] Effect of the sulfide group on photopolymerization kinetics of di(meth)acrylates
    Andrzejewska, E.
    Polymer Bulletin (Berlin), 1996, 37 (02):
  • [2] The photopolymerization kinetics features of naphthyl(Meth)acrylates in melts
    Sergey A. Chesnokov
    Roman S. Kovylin
    Ol’ga N. Mamysheva
    Georgy K. Fukin
    Vladimir K. Cherkasov
    Konstantin A. Lyssenko
    Journal of Polymer Research, 2014, 21
  • [3] The photopolymerization kinetics features of naphthyl(Meth)acrylates in melts
    Chesnokov, Sergey A.
    Kovylin, Roman S.
    Mamysheva, Ol'ga N.
    Fukin, Georgy K.
    Cherkasov, Vladimir K.
    Lyssenko, Konstantin A.
    JOURNAL OF POLYMER RESEARCH, 2014, 21 (05)
  • [4] Kinetics of Photopolymerization of Multifunctional (Meth)Acrylates in the Presence of an Aromatic Imidazole
    Begantsova, Yu. E.
    Konev, A. N.
    HIGH ENERGY CHEMISTRY, 2024, 58 (04) : 382 - 388
  • [5] Modelling the kinetics of photoinitiated polymerization of di(meth)acrylates
    Andrzejewska, E
    Linden, LA
    Rabek, JF
    POLYMER INTERNATIONAL, 1997, 42 (02) : 179 - 187
  • [6] The Photopolymerization of Thiol-(meth) allyl (meth) acrylates
    Zhang, Jing
    Long, He-nian
    Wang, Yue-chuan
    ACTA POLYMERICA SINICA, 2014, (11) : 1526 - 1531
  • [7] Photopolymerization of (Meth)Acrylates in the Presence of Polyheteroarylenes
    Sapozhnikov, D. A.
    Volkova, T. V.
    Sakharova, A. A.
    Gasanov, R. G.
    Voytekunas, V. Yu.
    Abadie, M. J. M.
    Sanchez, J. -Y.
    Vygodskii, Ya. S.
    POLYMER SCIENCE SERIES B, 2009, 51 (1-2) : 1 - 12
  • [8] Photopolymerization of (meth)acrylates in the presence of polyheteroarylenes
    D. A. Sapozhnikov
    T. V. Volkova
    A. A. Sakharova
    R. G. Gasanov
    V. Yu. Voytekunas
    M. J. M. Abadie
    J. -Y. Sanchez
    Ya. S. Vygodskii
    Polymer Science Series B, 2009, 51 : 1 - 12
  • [9] The effect of monomer structure on oxygen inhibition of (meth)acrylates photopolymerization
    Lee, TY
    Guymon, CA
    Jönsson, ES
    Hoyle, CE
    POLYMER, 2004, 45 (18) : 6155 - 6162
  • [10] Photopolymerization kinetics of 2-phenylethyl (meth)acrylates studied by photo DSC
    R. V. Ghorpade
    S. M. Bhosle
    S. Ponrathnam
    C. R. Rajan
    N. N. Chavan
    R. Harikrishna
    Journal of Polymer Research, 2012, 19
12345