Influence of sulfur trioxide in clinker on the hydration heat and physical properties of Portland cement

被引:10
|
作者
Yamashita, Makio [1 ]
Harada, Takumi [1 ]
Sakai, Etsuo [2 ]
Tsuchiya, Koichi [3 ,4 ]
机构
[1] Cement Co, Cement Res Inst, Mitsubishi Mat Corp, 2270 Yokoze, Yokoze, Saitama 3688504, Japan
[2] Tokyo Inst Technol, Sch Mat & Chem Technol, Meguro Ku, 2-12-1 Ookayama, Tokyo, Japan
[3] Res Ctr Struct Mat, Natl Inst Mat Sci, 1-2-1 Sengen, Tsukuba, Ibaraki 3050047, Japan
[4] Univ Tsukuba, Grad Sch Pure & Appl Sci, 1-1 Tennoudai, Tsukuba, Ibaraki 3055877, Japan
关键词
Cement clinker; SO3; Gypsum; C(3)A; Heat flow; Drying shrinkage; SULFATE; SO3; ALKALI; GYPSUM; REACTIVITY; PHASES; ALITE; FORM;
D O I
10.1016/j.conbuildmat.2020.118844
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
The cement industry has achieved stable usage of waste gypsum board in clinker production. However, few studies have focused on the heat of hydration and physical properties of cements with high-SO3 clinker with different C(3)A and gypsum contents. Clinker with different amounts of SO3 and coexisting C(3)A was prepared in an electric furnace. Cement samples were then prepared by adding gypsum. Increasing the clinker SO3 content accelerated the alite reaction and caused aluminate hydrate reaction to occur later. Compressive strength at 3 days increased with SO3 content whereas that after 28 days decreased. The drying shrinkage strain of mortar decreased with increasing SO3 content of the clinker and gypsum at each C(3)A content. The decrease of drying shrinkage attributed to SO3 in the clinker was smaller than that caused by gypsum SO3. As the clinker SO3 content increases, cement physical properties can be maintained by adjusting the gypsum content. (C) 2020 Elsevier Ltd. All rights reserved.
引用
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页数:10
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