A poly(vinylidene fluoride)-based gel electrolyte membrane for lithium batteries

被引：60
|
作者：
Appetecchi, GB [1 ]
Croce, F [1 ]
De Paolis, A [1 ]
Scrosati, B [1 ]
机构：
[1] Univ Roma La Sapienza, Dipartimento Chim, I-00185 Rome, Italy
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1999年 / 463卷 / 02期
关键词：
membrane; battery; lithium;
D O I：
10.1016/S0022-0728(98)00412-4
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Highly conducting, free standing polymer electrolyte membranes were prepared by gelification of an ethylene carbonate-propylene carbonate lithium methide solution in a poly(vinylidene fluoride)-chlorotrifluoroethylene copolymer matrix. The electrochemical characterization showed that these membranes have a room temperature conductivity of the order of 0.5 x 10(-3) cm(-1), an anodic break-down voltage exceeding 4.7 V vs. Li and good compatibility with the lithium metal electrode. These cm properties make these membranes of interest for the development of lithium metal and lithium ion batteries. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：248 / 252
页数：5
相关论文
共 50 条
  • [31] Plasticized microporous poly(vinylidene fluoride) separators for lithium-ion batteries.: II.: Poly(vinylidene fluoride) dense membrane swelling behavior in a liquid electrolyte -: Characterization of the swelling kinetics
    Saunier, J
    Alloin, F
    Sanchez, JY
    Barrière, R
    [J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2004, 42 (03) : 544 - 552
  • [32] Influence of nanometeric CuO on poly(vinylidene fluoride)-based composite gel polymer electrolyte
    Wang, BB
    Gu, LX
    [J]. MATERIALS LETTERS, 2002, 57 (02) : 361 - 363
  • [33] A lithium poly(pyromellitic acid borate) gel electrolyte membrane for lithium-ion batteries
    Guodong Xu
    Yubao Sun
    Rupesh Rohan
    Yunfeng Zhang
    Weiwei Cai
    Hansong Cheng
    [J]. Journal of Materials Science, 2014, 49 : 6111 - 6117
  • [34] A poly (vinylidene fluoride-hexafluoropropylene) based three-dimensional network gel polymer electrolyte for solid-state lithium-sulfur batteries
    Xia, Y.
    Liang, Y. F.
    Xie, D.
    Wang, X. L.
    Zhang, S. Z.
    Xia, X. H.
    Gu, C. D.
    Tu, J. P.
    [J]. CHEMICAL ENGINEERING JOURNAL, 2019, 358 : 1047 - 1053
  • [35] A lithium poly(pyromellitic acid borate) gel electrolyte membrane for lithium-ion batteries
    Xu, Guodong
    Sun, Yubao
    Rohan, Rupesh
    Zhang, Yunfeng
    Cai, Weiwei
    Cheng, Hansong
    [J]. JOURNAL OF MATERIALS SCIENCE, 2014, 49 (17) : 6111 - 6117
  • [36] Electrochemically stable poly (vinylidene fluoride)-polyurethane polymer gel electrolytes with polar β-phase in lithium batteries
    Xue, Nanxiang
    Wang, Wei
    Chen, Zhuangxin
    Heng, Yue
    Yuan, Zidan
    Xu, Ruijie
    Lei, Caihong
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2022, 907
  • [37] Poly(Ionic Liquid)-Based Composite Gel Electrolyte for Lithium Batteries
    Safa, Meer
    Adelowo, Ebenezer
    Chamaani, Amir
    Chawla, Neha
    Baboukani, Amin Rabiei
    Herndon, Marcus
    Wang, Chunlei
    El-Zahab, Bilal
    [J]. CHEMELECTROCHEM, 2019, 6 (13): : 3319 - 3326
  • [38] Poly(Vinylidene Fluoride)-Based Blends as New Binders for Lithium-Ion Batteries
    Zheng, Min
    Fu, Xuewei
    Wang, Yu
    Reeve, Jacqueline
    Scudiero, Louis
    Zhong, Wei-Hong
    [J]. CHEMELECTROCHEM, 2018, 5 (16): : 2288 - 2294
  • [39] Electrospun poly(vinylidene-fluoride)/POSS nanofiber membrane-based polymer electrolytes for lithium ion batteries
    Song, Xiaoyan
    Ding, Wanqing
    Cheng, Bowen
    Xing, Jinfeng
    [J]. POLYMER COMPOSITES, 2017, 38 (04) : 629 - 636
  • [40] Novel electrospun poly(vinylidene fluoride-co-hexafluoropropylene)-in situ SiO2 composite membrane-based polymer electrolyte for lithium batteries
    Raghaven, Prasanth
    Choi, Jae-Won
    Ahn, Jou-Hyeon
    Cheruvally, Gouri
    Chauhan, Ghanshyam S.
    Ahn, Hyo-Jun
    Nah, Changwoon
    [J]. JOURNAL OF POWER SOURCES, 2008, 184 (02) : 437 - 443
12345