Reckoning electromagnetic principles with polarimetric measurements of anisotropic optically active crystals

被引：32
|
作者：
Arteaga, Oriol [1 ]
Freudenthal, John [1 ]
Kahr, Bart [1 ]
机构：
[1] NYU, Dept Chem, New York, NY 10003 USA
来源：
JOURNAL OF APPLIED CRYSTALLOGRAPHY | 2012年 / 45卷
基金：
美国国家科学基金会;
关键词：
ACCURACY UNIVERSAL POLARIMETER; NON-ENANTIOMORPHOUS CRYSTAL; JONES MATRIX-METHOD; OBLIQUE-INCIDENCE; LAYERED MEDIA; MULTIPLE REFLECTIONS; SILVER THIOGALLATE; LIGHT-PROPAGATION; ALPHA-QUARTZ; BIREFRINGENCE;
D O I：
10.1107/S0021889812006085
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A method is introduced to correlate electromagnetic theory and polarimetric experiments for anisotropic optically active crystals at oblique angles of incidence. It is based on the 4 x 4 algebraic descriptions of light propagation in layered anisotropic media, which can be simplified to 2 x 2 matrices when multiple reflections are disregarded. Spectroscopic Mueller matrix measurements in transmission and at oblique angles of incidence have been made on two uniaxial crystals: alpha-quartz and silver thiogallate. Their optical activity tensors have been spectroscopically determined using the method presented here.
引用
收藏
页码：279 / 291
页数：13
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