Synthesis and electrochemical studies of a new series of pendant-armed hexaazamacrocyclic transition metal complexes

被引：10
|
作者：
Shakir, M
Mohamed, AK
Varkey, SP
Siddiqi, ZA
机构：
[1] Division of Inorganic Chemistry, Department of Chemistry, Aligarh Muslim University
来源：
TRANSITION METAL CHEMISTRY | 1996年 / 21卷 / 02期
关键词：
D O I：
10.1007/BF00136548
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of a new series of 14- and 16-membered hexaazamacrocyclic complexes has been achieved by the template condensation of ethylenediamine or 1,3-propylenediamine with formaldehyde and acetamide in a 1:2:1 molar ratio in the presence of metal chlorides. Octahedral structural formulae for selective metal complexes are proposed on the basis of physico-chemical and spectroscopic data. The redox behaviour in DMSO solution of the Cu-II complexes has been studied by cyclic voltammetry.
引用
收藏
页码：162 / 165
页数：4
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