Synthesis and electrochemical studies of a new series of pendant-armed hexaazamacrocyclic transition metal complexes

被引：10
|
作者：
Shakir, M
Mohamed, AK
Varkey, SP
Siddiqi, ZA
机构：
[1] Division of Inorganic Chemistry, Department of Chemistry, Aligarh Muslim University
来源：
TRANSITION METAL CHEMISTRY | 1996年 / 21卷 / 02期
关键词：
D O I：
10.1007/BF00136548
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of a new series of 14- and 16-membered hexaazamacrocyclic complexes has been achieved by the template condensation of ethylenediamine or 1,3-propylenediamine with formaldehyde and acetamide in a 1:2:1 molar ratio in the presence of metal chlorides. Octahedral structural formulae for selective metal complexes are proposed on the basis of physico-chemical and spectroscopic data. The redox behaviour in DMSO solution of the Cu-II complexes has been studied by cyclic voltammetry.
引用
收藏
页码：162 / 165
页数：4
相关论文
共 50 条
  • [1] Different nuclearity silver(I) complexes with novel tetracyano pendant-armed hexaazamacrocyclic ligands
    Fernández-Fernández, MD
    Bastida, R
    Macías, A
    Pérez-Lourido, P
    Valencia, L
    INORGANIC CHEMISTRY, 2006, 45 (05) : 2266 - 2275
  • [2] Synthesis and spectroscopic studies of dinuclear copper(II) complexes with new pendant-armed macrocyclic ligands
    Qingdao Zeng
    Jianjun Sun
    Shaohua Gou
    Keyu Zhou
    Jianglin Fang
    Hongyuan Chen
    Transition Metal Chemistry, 1998, 23 : 371 - 373
  • [3] Synthesis and spectroscopic studies of dinuclear copper(II) complexes with new pendant-armed macrocyclic ligands
    Zeng, QD
    Sun, JJ
    Gou, SH
    Zhou, KY
    Fang, JL
    Chen, HY
    TRANSITION METAL CHEMISTRY, 1998, 23 (04) : 371 - 373
  • [4] Lanthanide(III) nitrate complexes with a tetramethyl 4-(methyl)benzoate pendant-armed hexaazamacrocyclic ligand
    Ma Martinez-Sanchez, J.
    Bastida, R.
    Macias, A.
    Perez-Lourido, P.
    Valencia, L.
    INORGANICA CHIMICA ACTA, 2011, 378 (01) : 127 - 133
  • [5] Template synthesis and characterization of 12 and 14-membered pendant-armed tetraazamacrocyclic transition metal complexes: A photoelectron spectroscopic study
    Srivastava, S
    Kalam, A
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 2004, 34 (09): : 1529 - 1541
  • [6] Metal complexes with a new N4O3 amine pendant-armed macrocyclic ligand:: Synthesis, characterization, crystal structures, and fluorescence studies
    Vicente, M
    Bastida, R
    Lodeiro, C
    Macías, A
    Parola, AJ
    Valencia, L
    Spey, SE
    INORGANIC CHEMISTRY, 2003, 42 (21) : 6768 - 6779
  • [7] Different nuclearities of M(II) nitrate complexes (M = Co, Ni, Cu and Cd) with a tetrapyridyl pendant-armed hexaazamacrocyclic ligand
    Fernández-Fernández, MD
    Bastida, R
    Macías, A
    Valencia, L
    Pérez-Lourido, P
    POLYHEDRON, 2006, 25 (03) : 783 - 792
  • [8] Synthesis and characterization of cross-bridged cyclams and pendant-armed derivatives and structural studies of their copper(II) complexes
    1600, ACS, Washington, DC, USA (122):
  • [9] Complexes of pendant-armed cyclam derivatives with copper(II) perchlorate:: Synthesis and crystal structures
    Schoenherr, Thomas
    Seichter, Wilhelm
    Weber, Edwin
    POLYHEDRON, 2006, 25 (18) : 3463 - 3473
  • [10] Theoretical, biological and in silico studies of pendant-armed heteroleptic copper(II) phenolate complexes
    Arthi, P.
    Mahendiran, D.
    Shobana, S.
    Srinivasan, P.
    Rahiman, A. Kalilur
    JOURNAL OF MOLECULAR STRUCTURE, 2018, 1161 : 306 - 319
12345