Effects of slit-like pore confinement on the closed loop immiscibility in symmetric binary model mixtures: fundamental measure density functional approach

被引：13

作者：

Patrykiejew, A

Pizio, O

Pusztai, L

Sokolowski, S ^{[1
]}

机构：

[1] Marie Curie Sklodowska Univ, Dept Modelling Physicochem Proc, PL-20031 Lublin, Poland

[2] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico

[3] Hungarian Acad Sci, Inst Solid State Phys & Opt, Budapest, Hungary

来源：

MOLECULAR PHYSICS | 2003年 / 101卷 / 14期

关键词：

D O I：

10.1080/0026897031000099925

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We investigate the adsorption of model symmetric binary mixtures, exhibiting closed loop immiscibility in the bulk phase, in slit-like pores by using a density functional approach. Our focus is on changes in the closed loop phase diagram owing to confinement. We have found that, in general, confinement narrows immiscibility loops in the temperature-selectivity plane.

引用

页码：2219 / 2223

页数：5

共 10 条

[1] Phase behaviour of symmetric binary mixtures with partially miscible components in slit-like pores. Application of the fundamental measure density functional approach
Martinez, A
Pizio, O
Patrykiejew, A
Sokolowski, S
JOURNAL OF PHYSICS-CONDENSED MATTER, 2003, 15 (14) : 2269 - 2283
[2] Phase behavior of binary symmetric mixtures in pillared slit-like pores: A density functional approach
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Sokolowski, S.
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JOURNAL OF CHEMICAL PHYSICS, 2011, 134 (21):
[3] Mixtures of ions and amphiphilic molecules in slit-like pores: A density functional approach
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JOURNAL OF CHEMICAL PHYSICS, 2015, 142 (16):
[4] Effects of pore-pore correlations on capillary condensation in an ensemble of slit-like pores: Application of a density functional theory
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[5] Structure and phase transitions in a network-forming associating Lennard-Jones fluid in a slit-like pore: a density functional approach
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[6] Electric double layer capacitance of restricted primitive model for an ionic fluid in slit-like nanopores: A density functional approach
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JOURNAL OF CHEMICAL PHYSICS, 2012, 137 (23):
[7] On the phase behavior of model fluids with square-well attraction in slit-like pores. Density functional approach
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[8] Solvent primitive model of an electric double layer in slit-like pores: microscopic structure, adsorption and capacitance from a density functional approach
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CONDENSED MATTER PHYSICS, 2014, 17 (02)
[9] Density functional theory of electrolyte solutions in slit-like nanopores I. The RFD/WCA approach extended to non-restricted primitive model
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[10] Restricted primitive model for electrolyte solutions in slit-like pores with grafted chains: Microscopic structure, thermodynamics of adsorption, and electric properties from a density functional approach
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JOURNAL OF CHEMICAL PHYSICS, 2013, 138 (20):

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