Recent synthetic applications of the dealkoxycarbonylation reaction. Part 1. Dealkoxycarbonylations of malonate esters

被引：42
|
作者：
Krapcho, A. Paul [1 ]
机构：
[1] Univ Vermont, Dept Chem, Burlington, VT 05405 USA
来源：
ARKIVOC | 2007年
关键词：
dealkoxycarbonylations; Krapcho; decarbalkoxylations; malonate esters; TRANSANNULAR DIELS-ALDER; CONDENSED BETA-LACTAMS; NATURALLY-OCCURRING DIBENZOFURANS; RING-CLOSING METATHESIS; SOLID-PHASE SYNTHESIS; ALPHA-CYANO ESTERS; ENANTIOSELECTIVE SYNTHESIS; STEREOSELECTIVE-SYNTHESIS; CONVENIENT SYNTHESIS; ASYMMETRIC-SYNTHESIS;
D O I：
10.3998/ark.5550190.0008.201
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The purpose of this review is to update ( publications from 1981 to mid 2006) the synthetic applications of dealkoxycarbonylations of malonate esters, beta-keto esters (and related esters with alpha-substituted electron-withdrawing functionalities) induced by heating with water or with water in the presence of salts (such as NaCN, NaCl or LiCl) in dipolar aprotic solvents. The presentation will be divided in two parts. In Part 1, discussion will focus on the dealkoxycarbonylations of malonate esters. Part 2 ( to follow as a separate paper) will deal with the dealkoxycarbonylations of beta-keto esters and alpha-cyano esters (and related analogues).
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页码：1 / 53
页数：53
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