Stabilization of tetrameric metavanadate ion by tris(1,10-phenanthroline)cobalt(III): synthesis, spectroscopic, and X-ray structural study of [Co(phen)3]3(V4O12)2Cl • 27H2O

被引：8

作者：

Sharma, Raj Pal ^{[1
]}

Ajnesh, Singh ^{[1
]}

Venugopalan, Paloth ^{[1
]}

Dansby-Sparks, Royce ^{[2
]}

Xue, Zi-Ling ^{[2
]}

Rossetti, Stefano ^{[3
]}

Ferretti, Valeria ^{[4
,5
]}

机构：

[1] Panjab Univ, Dept Chem, Chandigarh 160014, India

[2] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

[3] Univ Ferrara, Dipartimento Chim, ISOF, CNR, I-44100 Ferrara, Italy

[4] Univ Ferrara, Ctr Strutturist Diffrattometr, I-44100 Ferrara, Italy

[5] Univ Ferrara, Dipartimento Chim, I-44100 Ferrara, Italy

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2010年 / 63卷 / 17期

基金：

美国国家科学基金会;

关键词：

Cobalt(III); Second sphere coordination chemistry; 1; 10-Phenanthroline; Polyoxovanadate; X-ray crystallography; CRYSTAL-STRUCTURE; PHOTOPHYSICAL PROPERTIES; FUTURE PERSPECTIVES; ANION; RECOGNITION; COMPLEXES; COORDINATION; REFINEMENT; SULFATE; BOND;

D O I：

10.1080/00958972.2010.504831

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new complex salt of composition [Co(phen)3]3(V4O12)2Cl 27H2O (phen = 1,10-phenanthroline and [V4O12]4- = tetrameric metavanadate, dodecaoxotetravanadate ion) was synthesized by the reaction of appropriate salts in aqueous medium. The complex salt has been characterized by elemental analyses, thermogravimetric analysis, cyclic voltammetry, FT-IR, and UV-Vis spectroscopies, solubility product and conductance measurements. Single crystal X-ray structure determination revealed ionic structure consisting of three complex cations, [Co(phen)3]3+, two [V4O12]4- anions, one chloride and 27 lattice water molecules. Detailed structural and spectroscopic analyses of [Co(phen)3]3(V4O12)2Cl 27H2O showed that the large anion is stabilized by large cationic metal complex as there is preferred shape compatibility that leads to a large number of lattice-stabilizing non-covalent interactions.

引用

页码：3016 / 3027

页数：12

共 50 条

[21] Crystal structure of the [aqua(ethylenediaminetetraacetato)bariate] Tris(1,10-phenanthroline)nickel crystal hydrate [Ni(Phen)3][Ba(Edta)(H2O)] · 12H2O
Sadikov, G.G.
Antsyshkina, A.S.
Sergienko, V.S.
Poznyak, A.L.
Zhurnal Neorganicheskoj Khimii, 2002, 47 (01): : 54 - 65
[22] Crystal structure of the tris(1,10-phenanthroline)nickel aqua(ethylenediaminetetraacetato)bariate crystal hydrate [Ni(Phen)3][Ba(Edta)(H2O)]•12H2O
Sadikov, GG
Antsyshkina, AS
Sergienko, VS
Poznyak, AL
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2002, 47 (01) : 49 - 59
[23] Synthesis, Thermal Stability, and Structure of Bis(citrato)germanates: [Co(Phen)3][Ge(HCit)2] • 2H2O, [Fe(Phen)3][Ge(HCit)2] • 4H2O (H4Cit = Citric Acid, Phen=1,10-Phenanthroline)
Seifullina, I. I.
Martsinko, E. E.
Chebanenko, E. A.
Pirozhok, O. V.
Dyakonenko, V. V.
Shihkina, S. V.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2017, 43 (08) : 505 - 511
[24] Synthesis, thermal stability, and structure of bis(citrato)germanates: [Co(Phen)3][Ge(HCit)2] · 2H2O, [Fe(Phen)3][Ge(HCit)2] · 4H2O (H4Cit = citric acid, Phen = 1,10-phenanthroline)
I. I. Seifullina
E. E. Martsinko
E. A. Chebanenko
O. V. Pirozhok
V. V. Dyakonenko
S. V. Shihkina
Russian Journal of Coordination Chemistry, 2017, 43 : 505 - 511
[25] The first well characterized Fe(phen)Cl3 complex:: structure of aquo mono(1,10-phenanthroline)iron(III) trichloride:: [Fe(phen)Cl3(H2O)]
Kulkarni, P
Padhye, S
Sinn, E
POLYHEDRON, 1998, 17 (16) : 2623 - 2626
[26] Structure of bischloro tris(1,10-phenanthroline) copper (II) dichloromethane solvate nonahydrate:: [Cu (phen)3] Cl2•CH2Cl2•9H2O
Jian, FF
Lin, JH
Zhang, SS
CHINESE JOURNAL OF CHEMISTRY, 2001, 19 (08) : 772 - 777
[27] THE YTTRIUM CHLORIDE-1,10-PHENANTHROLINE INTERACTION - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF THE COMPLEX [Y(OH)(H2O)2(PHEN)2]2CL4.2(PHEN).MEOH
GRILLONE, MD
BENETOLLO, F
BOMBIERI, G
POLYHEDRON, 1991, 10 (18) : 2171 - 2177
[28] Weak C-H•••F-C interactions in carboxylate anion binding: Synthesis, spectroscopic and X-ray structural studies of [Co(phen)2CO3]2 (C7H3O2FCl)Cl•11H2O and [Co(phen)2CO3](C7H3NO4Cl)•6H2O
Singh, A.
Sharma, R. P.
Aree, T.
Venugopalan, P.
JOURNAL OF CHEMICAL SCIENCES, 2010, 122 (05) : 739 - 750
[29] Weak C-H…F-C interactions in carboxylate anion binding: Synthesis, spectroscopic and X-ray structural studies of [Co(phen)2CO3]2 (C7H3O2FCl)Cl·11H2O and [Co(phen)2CO3](C7H3NO4Cl)·6H2O
A. Singh
R. P. Sharma
T. Aree
P. Venugopalan
Journal of Chemical Sciences, 2010, 122 : 739 - 750
[30] Kinetics and mechanism of oxidation of thiosulphate by the complex ion [MnIV3(μ-O)4(phen)4(H2O)2]4+ (phen = 1,10-phenanthroline) in weakly acidic aqueous media
Dilip Maji
Rupendranath Banerjee
Transition Metal Chemistry, 2001, 26 : 544 - 550

← 1 2 3 4 5 →