Potassium dicyanoargentate(I) 1,4,7,10,13,16-hexaoxacyclooctadecane

被引:5
|
作者
Schlueter, JA [1 ]
Geiser, U [1 ]
机构
[1] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA
关键词
D O I
10.1107/S0108270103014318
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The crystal structure of the title compound, K[Ag(CN)(2)].-C12H24O6, conventionally denoted K(18-crown-6)Ag(CN)(2), where 18-crown-6 is 1,4,7,10,13,16-hexaoxacyclooctadecane, is characterized by closely packed linear chains formed by the coordination of the nitrile N atoms of the [Ag(CN)(2)](-). anions to the K+ cations. The K atoms lie on centers of inversion and are additionally bound to the six O atoms of the crown ether.
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页码:M325 / M327
页数:3
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